220691-39-4

Basic information

• Product Name: phenyl O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-(1-3)-4-O-(acetyl-1-13C)-6-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside
• Synonyms: phenyl O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-(1-3)-4-O-(acetyl-1-13C)-6-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside
• CAS NO: 220691-39-4
• Molecular Weight: 951.108
• Mol File: 220691-39-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: phenyl O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-(1-3)-4-O-(acetyl-1-13C)-6-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-(1-3)-4-O-(acetyl-1-13C)-6-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside(220691-39-4)
• EPA Substance Registry System: phenyl O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-(1-3)-4-O-(acetyl-1-13C)-6-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside(220691-39-4)

Safety Data

• Hazardous Substances Data: 220691-39-4(Hazardous Substances Data)

Upstream product

• 424820-76-8 phenyl 2,3,4-tri-O-benzyl-α-L-fucopyranosyl-(1->3)-4,6-O-benzylidene-2-deoxy-2-phthalimido-1-thio-β-L-glucopyranoside 
• 183875-25-4 phenyl 2,3,4-tri-O-benzyl-1-thio-α-L-fucopyranoside 
• 1563-79-7 [1-13C]-acetic acid 
• 424820-77-9 phenyl O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-(1-3)-6-O-benzyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 
• 127061-09-0 phenyl 4,6-di-O-benzylidene-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside 

Downstream Products

• 424820-90-6 N-[6-benzyloxymethyl-5-(3,5-bis-benzyloxy-6-benzyloxymethyl-4-hydroxy-tetrahydro-pyran-2-yloxy)-2-(5-carboxy-pentyloxy)-4-(3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yl]-phthalamic acid 
• 424820-89-3 N-[6-benzyloxymethyl-5-(3,5-bis-benzyloxy-6-benzyloxymethyl-4-hydroxy-tetrahydro-pyran-2-yloxy)-2-(5-carboxy-pentyloxy)-4-(3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran-3-yl]-phthalamic acid 

Relevant articles and documents

Solid-phase synthesis of oligosaccharides and on-resin quantitative monitoring using gated decoupling 13C NMR

A general strategy for solid-phase oligosaccharide synthesis capable of nondestructive quantitative monitoring has been developed. The synthesis was carried out on TentaGel using thioglycosides as glycosylating agents and dimethylthiomethylsulfonium triflate as the activator. An acylsulfonamide linker was introduced to cleave the oligosaccharide from the resin. The solid-phase reactions were monitored quantitatively by using the inverse gated decoupling technique of 13C NMR, where two 13C-enriched markers were used to monitor the reactions: one was 13C-enriched glycine incorporated as a part of the linker and as an internal standard, and the other was a 13C-enriched acetyl group used as a protecting group of the glycosylation reagent. A representative synthesis of sialyl Lewis X branched tetrasaccharide was demonstrated.