22082-95-7

Basic information

• Product Name: 2-(2-fluorophenyl)naphthalene
• Synonyms: 2-(2-fluorophenyl)naphthalene
• CAS NO: 22082-95-7
• Molecular Weight: 222.262
• Mol File: 22082-95-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 2-(2-fluorophenyl)naphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-fluorophenyl)naphthalene(22082-95-7)
• EPA Substance Registry System: 2-(2-fluorophenyl)naphthalene(22082-95-7)

Safety Data

• Hazardous Substances Data: 22082-95-7(Hazardous Substances Data)

Upstream product

• 580-13-2 2-bromonaphthalene 
• 3857-83-8 2-naphthyl triflate 
• 1072-85-1 o-fluorobromobenzene 
• 1145-08-0 naphthalen-2-yl N,N-dimethylsulfamic acid 
• 1993-03-9 o-fluorophenylboronic acid 
• 7385-85-5 naphthalen-2-yl tosylate 
• 16463-37-9 potassium ortho-fluorobenzoate 
• 93-04-9 2-Methoxynaphthalene 
• 346656-39-1 2-(2-fluorophenyl)-5,5-dimethyl-[1,3,2]dioxaborinane 
• 135-19-3 β-naphthol 

Relevant articles and documents

Nickel-catalyzed cross-coupling of aryl methyl ethers with aryl boronic esters

(Chemical Equation Presented) To C-OMe and go: The title reaction, involving cleavage of a C-OMe bond, is demonstrated for the coupling of aryl methyl ethers on fused aromatic systems, such as naphthalene and phenanthrene, as well as anisoles containing electron-withdrawing groups with a wide range of boronic esters. cod=cycloocta-1,5-diene, Cy=cyclohexyl.

Tetraethylphosphorodiamidate-Directed Metalation Group: Directed Ortho and Remote Metalation, Cross Coupling, and Remote Phospha Anionic Fries Rearrangement Reactions

The linked directed ortho and remote metalation (DoM and DreM) and cross-coupling reactions of aryl phosphorodiamidates (Ar-OP(O)(NEt2)2) is reported. The o-iodo and o-boronato aryl tetraethylphosphorodiamidates 3, prepared by DoM, undergo orthogonal Ni- and Pd-catalyzed Suzuki-Miyaura cross coupling to furnish biaryls 4 and 5 in good to excellent yields. Silicon group protection of biaryl 4 via DoM followed by previously unobserved DreM phospha anionic Fries rearrangement affords biaryls 11 which, under acidic conditions, furnish oxaphosphorine oxides 12.

Rapid nickel-catalyzed suzuki-miyaura cross-couplings of aryl carbamates and sulfamates utilizing microwave heating

High-speed and scalable nickel-catalyzed cross-coupling of arylboronic acids with aryl carbamates and sulfamates is achieved by using sealed-vessel microwave processing.(Figure Presented)