221129-39-1Relevant articles and documents
Metalation of 3-trimethylsilyl propargyl chloride: A stereoselective access to trans-propargylic oxiranes
Chemla, Fabrice,Bernard, Nicolas,Normant, Jean F.
, p. 75 - 78 (2007/10/03)
The metalation of 3-trimethylsilyl-1-chloroprop-2-yne and the subsequent reaction with aldehydes affords stereospecifically anti-chlorohydrins which give after treatment with potassium fluoride and NaOH propargylic epoxides with good to excellent yields.