22181-31-3Relevant articles and documents
The α-Effect in Benzyl Transfers from Benzylphenylmethyl Sulfonium Salts to N-Methylbenzohydroxamate Anions
Fountain,Tad-y, Darlene B.,Paul, Timothy W.,Golynskiy, Mikhail V.
, p. 6547 - 6553 (2007/10/03)
The investigation of the occurrence of the α-effect in group transfers from phenyldialkyl sulfonium ions where one alkyl group is benzyl allows an assay of the effect of changing the nature of the C atom being transferred. The size of the α-effect responds to increasing electron demand, as methyl transfers do. Quantitative relationships between the size of the α-effect are established from both the nucleophilic side and the leaving group side of the SN2 transition state.
Compounds with potential enzyme inhibitory acitivity. Hydroxylamine analogs of 2-propynylamine.
Moore,Cannon,McIsaac,Ho
, p. 45 - 48 (2007/10/06)
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