2223-67-8Relevant articles and documents
EPIMERIZATION OF ENDO- AND EXO-BORNEOLS IN THE PRESENCE OF AMMONIA AND/OR HYDROGEN ON A FUSED IRON CATALYST
Glebov, L. S.,Shuikin, A. N.,Kliger, G. A.,Loktev, S. M.
, p. 1985 - 1987 (1990)
Epimerization of borneols was noted upon their reaction with ammonia and/or hydrogen on fused iron catalyst.Borneols are hydroaminated to give bornylamines with predominance of the endo isomer.
The endo- and exo-1,7,7-Trimethylbicyclo-heptan-2-amines (Bornan-2-amines) and Their Acetamides
Carman, Raymond M.,Greenfield, Kay L.
, p. 1785 - 1790 (2007/10/02)
Melting points provide a poor method for differentiation between the exo and endo N-(bornan-2-yl)-acetamides, and have led to errors by previous workers.Spectral differences leading to unambiguous assignment are discussed in this paper.Trapping of the bornan-2-yl carbenium ion with acetonitrile leads to exo products.