222402-52-0

Basic information

• Product Name: [Re(1,1,1-tris(diphenylphosphanylmethyl)ethane)(CO)2]triflate
• CAS NO: 222402-52-0
• Molecular Weight: 1015.98
• Mol File: 222402-52-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [Re(1,1,1-tris(diphenylphosphanylmethyl)ethane)(CO)2]triflate(CAS DataBase Reference)
• NIST Chemistry Reference: [Re(1,1,1-tris(diphenylphosphanylmethyl)ethane)(CO)2]triflate(222402-52-0)
• EPA Substance Registry System: [Re(1,1,1-tris(diphenylphosphanylmethyl)ethane)(CO)2]triflate(222402-52-0)

Safety Data

• Hazardous Substances Data: 222402-52-0(Hazardous Substances Data)

Upstream product

• 51406-11-2 Re(CO)2(η3-1,1,1-tris(diphenylphosphino)ethane)Cl 
• 166989-33-9 (CH₃C(CH₂P(C₆H₅)2)3)Re(CO)2(H) 
• 333-27-7 methyl trifluoromethanesulfonate 
• 2923-28-6 silver trifluoromethanesulfonate 
• 1493-13-6 trifluorormethanesulfonic acid 
• 166989-37-3 (CH₃C(CH₂P(C₆H₅)2)3)Re(CO)2⁽¹⁺⁾*BF₄^(1-)=[(CH₃C(CH₂P(C₆H₅)2)3)Re(CO)2]BF₄ 
• 2926-30-9 sodium triflate 
• 166989-35-1 [(MeC(CH2PPh2)3)Re(CO)2(η(2)-H2)]BF4 

Downstream Products

• 222402-67-7 fac-[Re(η¹-NCO)(CO)2(MeC(CH2PPh2)3)] 
• 1431298-11-1 fac-[Re(η¹-PCO)(CO)2(MeC(CH2PPh2)3)] 
• 222402-62-2 Re(CH₃C(CH₂P(C₆H₅)2)3)(CO)2SeCN 
• 222402-62-2 Re(CH₃C(CH₂P(C₆H₅)2)3)(CO)2NCSe 
• 222402-61-1 Re(CH₃C(CH₂P(C₆H₅)2)3)(CO)2SCN 
• 222402-61-1 Re(CH₃C(CH₂P(C₆H₅)2)3)(CO)2NCS 
• 222402-73-5 Re(CH₃C(CH₂P(C₆H₅)2)3)(CO)2SeCNCH₃⁽¹⁺⁾*CF₃SO₃^(1-) = [Re(CH₃C(CH₂P(C₆H₅)2)3)(CO)2SeCNCH₃]CF₃SO₃ 
• 222402-71-3 Re(CH₃C(CH₂P(C₆H₅)2)3)(CO)2SCNCH₃⁽¹⁺⁾*CF₃SO₃^(1-) = [Re(CH₃C(CH₂P(C₆H₅)2)3)(CO)2SCNCH₃]CF₃SO₃ 
• 222402-69-9 Re(CH₃C(CH₂P(C₆H₅)2)3)(CO)2CNCH₃⁽¹⁺⁾*CF₃SO₃^(1-) = [Re(CH₃C(CH₂P(C₆H₅)2)3)(CO)2CNCH₃]CF₃SO₃ 
• 166989-47-5 (CH₃C(CH₂P(C₆H₅)2)3)Re(CO)2(CC(H)C₆H₁₃)⁽¹⁺⁾*B(C₆H₅)4^(1-)=[(CH₃C(CH₂P(C₆H₅)2)3)Re(CO)2(CC(H)C₆H₁₃)][B(C₆H₅)4] 
• 166989-43-1 (CH₃C(CH₂P(C₆H₅)2)3)Re(CO)2(CC(H)C₆H₅)⁽¹⁺⁾*B(C₆H₅)4^(1-)=[(CH₃C(CH₂P(C₆H₅)2)3)Re(CO)2(CC(H)C₆H₅)][B(C₆H₅)4] 
• 166989-45-3 (CH₃C(CH₂P(C₆H₅)2)3)Re(CO)2(CC(H)COOC₂H₅)⁽¹⁺⁾*B(C₆H₅)4^(1-)=[(CH₃C(CH₂P(C₆H₅)2)3)Re(CO)2(CC(H)COOC₂H₅)][B(C₆H₅)4] 
• 222402-55-3 ReCN(CH₃C(CH₂P(C₆H₅)2)3)(CO)2 

Relevant articles and documents

Substitution of labile triflate in [(triphos)Re(CO)2(OTf)]: A new synthetic route to mononuclear and dinuclear Re(I) complexes

New synthetic routes to the neutral complex [(triphos)Re(CO)2(OTf)] [triphos = MeC(CH2PPh2)3, OTf = CF3SO3-] (3) are reported. The triflate ligand in 3 is labile and can be easil