222839-16-9Relevant articles and documents
Synthesis of new atropisomeric bisphosphine ligands bearing chiral phospholane and their use in asymmetric hydrogenation
Fujie, Naoto,Matsui, Manko,Achiwa, Kazuo
, p. 436 - 439 (1999)
Novel chiral bisphosphine ligands bearing (2S,5S)-dimethylphospholano group on a chiral biphenyl back-bone were designed and prepared. Asymmetric hydrogenations of a ketone and an olefin with the rhodium(I) complex catalysts prepared in situ from [Rh(COD)