22474-71-1Relevant articles and documents
BEITRAEGE ZUR CHEMIE DES IODOPENTAFLUORIDS. TEIL IV. IF5 EIN SELEKTIVES OXIDATIVES FLUORIERUNGSMITTEL FUER ORGANOPHOSPHOR(III)-VERBINDUNGEN
Frohn, H. J.,Maurer, H.
, p. 73 - 82 (2007/10/02)
Aryl-and alkylphosphines R3P, R2PF, R2PCl, and RPCl2 are oxidized by IF5 to the corresponding fluorophosphoranes in a fast one step-reaction at or below 0 deg C.The only coproduct is elemental iodine.IF3 or IF as reduction products of IF5 are not observed.Fission of P-C - bonds by from I2 and IF5 is negligible under reaction conditions.In alkylfluorophosphoranes fluoride donor-acceptor-interactions between fluorophosphoranes and IF5 are observed.