22490-19-3Relevant articles and documents
Leveraging the micellar effect: Gold-catalyzed dehydrative cyclizations in water at room temperature
Minkler, Stefan R. K.,Isley, Nicholas A.,Lippincott, Daniel J.,Krause, Norbert,Lipshutz, Bruce H.
supporting information, p. 724 - 726 (2014/03/21)
The first examples of gold-catalyzed cyclizations of diols and triols to the corresponding hetero- or spirocycles in an aqueous medium are presented. These reactions take place within nanomicelles, where the hydrophobic effect is operating, thereby driving the dehydrations, notwithstanding the surrounding water. By the addition of simple salts such as sodium chloride, reaction times and catalyst loadings can be significantly decreased.
Synthesis of multisubstituted 2-(dihydrofuran-2(3H)-ylidene)acetates via intramolecular carboalkoxylation by platinum-olefin catalyst system
Nakamura, Itaru,Ching, Siew Chan,Araki, Toshiharu,Terada, Masahiro,Yamamoto, Yoshinori
, p. 309 - 312 (2008/09/19)
(Chemical Equation Presented) The cyclization of 6-(1-alkoxyethyl)hex-2- ynoates in the presence of a platinum-olefin catalyst system gave the corresponding multisubstituted 2-(dihydrofuran-2(3H)-ylidene)acetates in good to high yields. The Z/E selectivit
