224949-94-4

Basic information

• Product Name: (Z)-<8,8,8-2H3>-1-(benzyloxy)-3,7-dimethyl-6-octene
• Synonyms: (Z)-<8,8,8-2H3>-1-(benzyloxy)-3,7-dimethyl-6-octene
• CAS NO: 224949-94-4
• Molecular Weight: 249.369
• Mol File: 224949-94-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Z)-<8,8,8-2H3>-1-(benzyloxy)-3,7-dimethyl-6-octene(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-<8,8,8-2H3>-1-(benzyloxy)-3,7-dimethyl-6-octene(224949-94-4)
• EPA Substance Registry System: (Z)-<8,8,8-2H3>-1-(benzyloxy)-3,7-dimethyl-6-octene(224949-94-4)

Safety Data

• Hazardous Substances Data: 224949-94-4(Hazardous Substances Data)

Upstream product

• 111675-13-9 (Z)-1-(benzyloxy)-3,7-dimethyl-6-octen-8-ol 
• 224949-91-1 methyl (Z)-8-(benzyloxy)-2,6-dimethyl-2-octenoate 
• 224950-15-6 (Z)-1-(benzyloxy)-3,7-dimethyl-6-octen-8-al 
• 87359-89-5 4-methyl-6-(benzyloxy)-1-hexanal 
• 96154-40-4 3,7-dimethyl-6-octenyl benzyl ether 
• 224949-93-3 (Z)-<8,8-2H2>-1-(benzyloxy)-3,7-dimethyl-6-octen-8-yl chloride 

Relevant articles and documents

New Lewis-acidic molybdenum(II) and tungsten(II) catalysts for intramolecular carbonyl erie and prins reactions. Reversal of the stereoselectivity of cyclization of citronellal

New Mo(II) complexes BnEt3N+[Mo(CO)4ClBr2]- (A) and Mo(CO)5(OTf)2 (B) and their W(II) congeners D and E have been developed as catalysts for the title reactions. Unlike other Lewis acids, the latter catalysts exhibit cis-stereoselectivity in the cyclization of citronellal (1 → 3 with A and 1 → 5 with B). Isotopic labeling allowed formulation of the reaction mechanism, according to which these complexes act as bulky Lewis acids, η1- coordinated to the carbonyl oxygen. The stereochemistry appears to be controlled by the protruding ligand L(p), which dictates the boatlike transition state III. The kinetically formed cis-alkenol 3 can be equilibrated by [Mo(CO)4Br2]2 (C) or ZnCl2 to its trans-epimer 2 via a retro-ene reaction.