22565-68-0

Basic information

• Product Name: methyl (1R,4aS,9R,10aR)-9-acetoxy-1,2,3,4,4a,9,10,10a-octahydro-1,4a-dimethyl-7-(1-methylethyl)phenanthrene-1-carboxylate
• CAS NO: 22565-68-0
• Molecular Weight: 372.505
• Mol File: 22565-68-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl (1R,4aS,9R,10aR)-9-acetoxy-1,2,3,4,4a,9,10,10a-octahydro-1,4a-dimethyl-7-(1-methylethyl)phenanthrene-1-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (1R,4aS,9R,10aR)-9-acetoxy-1,2,3,4,4a,9,10,10a-octahydro-1,4a-dimethyl-7-(1-methylethyl)phenanthrene-1-carboxylate(22565-68-0)
• EPA Substance Registry System: methyl (1R,4aS,9R,10aR)-9-acetoxy-1,2,3,4,4a,9,10,10a-octahydro-1,4a-dimethyl-7-(1-methylethyl)phenanthrene-1-carboxylate(22565-68-0)

Safety Data

• Hazardous Substances Data: 22565-68-0(Hazardous Substances Data)

Upstream product

• 127-25-3 methyl abietate 
• 546-67-8 lead(IV) tetraacetate 

Downstream Products

• 18492-76-7 methyl (1R,4aS,10aR)-1,2,3,4,4a,10a-hexahydro-1,4a-dimethyl-7-(1-methylethyl)phenanthrene-1-carboxylate 
• 25236-85-5 methyl (1R,4aS,9R,10aR)-1,2,3,4,4a,9,10,10a-octahydro-9-methoxy-1,4a-dimethyl-7-(1-methylethyl)phenanthrene-1-carboxylate 

Relevant articles and documents

STUDIES ON ALLYLIC OXIDATION REACTIONS OF METHYL ABIETATE

Allylic oxidation reactions of methyl abietate (2) with selenium dioxide and lead tetraacetate have been studied in different solvents.Oxidation of methyl abietate (2) with selenium dioxide in acetic anhydride furnished methyl 7α-O-acetyl dehydroabietate (5b) in 68 percent yield.