22566-53-6

Basic information

• Product Name: 1,4-Cyclohexadiene, 1-(1,1-dimethylethyl)-4-methoxy-
• CAS NO: 22566-53-6
• Molecular Formula: C11H18O
• Molecular Weight: 166.263
• Mol File: 22566-53-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1,4-Cyclohexadiene, 1-(1,1-dimethylethyl)-4-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-Cyclohexadiene, 1-(1,1-dimethylethyl)-4-methoxy-(22566-53-6)
• EPA Substance Registry System: 1,4-Cyclohexadiene, 1-(1,1-dimethylethyl)-4-methoxy-(22566-53-6)

Safety Data

• Hazardous Substances Data: 22566-53-6(Hazardous Substances Data)

Upstream product

• 5396-38-3 1-(tert-butyl)-4-methoxybenzene 

Downstream Products

• 5234-62-8 4-tert.-Butyl-cyclohex-3-en-1-on 
• 113778-45-3 (3S^*,4R^*)-4-(1,1-dimethylethyl)-3-hydroxycyclohexanone 
• 113778-48-6 (3R^*,4R^*)-4-(1,1-dimethylethyl)-3-hydroxycyclohexanone 
• 113778-86-2 c-3-Hydroxy-t-4-tert.butyl-r-1-cyclohexanol 
• 113778-85-1 (1S,3R,4S)-4-tert-Butyl-cyclohexane-1,3-diol 
• 113778-87-3 cis-3-Hydroxy-trans-4-tert.-butylcyclohexanol 
• 5396-38-3 1-(tert-butyl)-4-methoxybenzene 

Relevant articles and documents

A Practical and Chemoselective Ammonia-Free Birch Reduction

A novel protocol for a significantly improved, practical, and chemoselective ammonia-free Birch reduction mediated by bench-stable sodium dispersions and recoverable 15-crown-5 ether is reported. A broad range of aromatic and heteroaromatic compounds is reduced with excellent yields.

Reduction method of electronic salt reaction liquid and unsaturated aromatic hydrocarbon compound

To the reduction method, tetrahydrofuran is used as a solvent and an electron trapping agent, metal lithium is used as a reducing agent, tertiary butanol is used as a reducing agent, and the unsaturated aromatic hydrocarbon compound is reduced under -10 - 0 °C conditions. The raw material tetrahydrofuran is used in the invention. Metal lithium and tert-butyl alcohol are all conventional chemical products, and are simple and easy to obtain. After the reaction is finished, excess lithium and solvent are recovered, and directly used to realize low cost, low pollution and high yield.