226065-37-8

Basic information

• Product Name: Hydrazinecarboxylic acid, 1-phenyl-, 1,1-dimethylethyl ester
• CAS NO: 226065-37-8
• Molecular Formula: C11H16N2O2
• Molecular Weight: 208.26
• Mol File: 226065-37-8.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Hydrazinecarboxylic acid, 1-phenyl-, 1,1-dimethylethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Hydrazinecarboxylic acid, 1-phenyl-, 1,1-dimethylethyl ester(226065-37-8)
• EPA Substance Registry System: Hydrazinecarboxylic acid, 1-phenyl-, 1,1-dimethylethyl ester(226065-37-8)

Safety Data

• Hazardous Substances Data: 226065-37-8(Hazardous Substances Data)

Upstream product

• 108-86-1 bromobenzene 
• 870-46-2 t-butoxycarbonylhydrazine 
• 591-50-4 iodobenzene 
• 24424-99-5 di-tert-butyl dicarbonate 
• 17763-67-6 Phenyl triflate 

Downstream Products

• 3422-01-3 tert-butyl phenylcarbamate 
• 942-01-8 1,2,3,4-tetrahydrocarbazole 
• 91-55-4 2,3-dimethylindole 
• 681815-36-1 N'-[3,5-bis-(N'-tert-butoxycarbonyl-N'-phenyl-hydrazino)-phenyl]-N-phenylhydrazinecarboxylic acid tert-butyl ester 
• 912968-79-7 N-(tert-butoxycarbonyl)-N'-[2-(1,3-dioxolan-2-yl)phenyl]-N-phenylhydrazine 
• 21650-49-7 (E)-1-(4-methoxyphenyl)-2-phenyldiazene 
• 1072190-46-5 phenyl-(2-phenyl-5-trifluoromethyl-indol-1-yl)carbamic acid tert-butyl ester 
• 1072190-51-2 phenyl(2-pyridin-2-yl-indol-1-yl)carbamic acid tert-butyl ester 
• 1264670-17-8 [2-(6-methoxy-naphthalen-2-yl)-indol-1-yl]phenylcarbamic acid tert-butyl ester 
• 1072190-56-7 1-(tert-butoxycarbonylphenylamino)-2-cyclopropyl-1H-indole-6-carboxylic acid tert-butyl ester 
• 1264670-22-5 (2-diethylaminomethyl-indol-1-yl)phenylcarbamic acid tert-butyl ester 
• 1072190-44-3 (6-fluoro-2-phenyl-indol-1-yl)phenylcarbamic acid tert-butyl ester 
• 1072190-47-6 (6-methoxy-2-phenyl-indol-1-yl)phenylcarbamic acid tert-butyl ester 

Relevant articles and documents

Starazo triple switches - synthesis of unsymmetrical 1,3,5-tris(arylazo)benzenes

Multistate switches allow to drastically increase the information storage capacity and complexity of smart materials. In this context, unsymmetrical 1,3,5-tris(arylazo)benzenes - 'starazos' - which merge three photoswitches on one benzene ring, were succe

A reusable and naked-eye molecular probe with aggregation-induced emission (AIE) characteristics for hydrazine detection

We report a fluorogenic probe for naked-eye sensing of hydrazine in solution and in the gaseous phase. The probe based on tetraphenylethylene (TPE) with aggregation-induced emission (AIE) characteristics shows OFF-ON fluorescence as observed by thin-layer chromatography (TLC) upon treatment with hydrazine. Specifically, the fluorescence of the probe was quenched due to the attached NN group, which can be reduced to -NH-NH- in the presence of hydrazine to turn on the fluorescence. The reduced intermediate can be easily oxidized in air to regenerate the original probe for recyclable usage. Both fluorometric and colorimetric readings were achieved by TLC with high sensitivity and excellent selectivity. This study thus represents a simple example of a reusable and naked-eye molecular probe for monitoring environmental hazards. Finally, the probe has also been applied to detect hydrazine in live cells.

Synthesis of N-aryl hydrazides by copper-catalyzed coupling of hydrazides with aryl iodides.

[reaction--see text] A convenient method for intermolecular N-arylation of hydrazides with substituted aryl iodides in the presence of a copper catalyst and Cs(2)CO(3) is reported. The C-N coupling of N-Boc hydrazine with para- and meta-substituted aryl iodides afforded the N-arylated products A, regioselectively. A reversal in regioselectivity is observed for the arylation of benzoic hydrazide with ortho-substituted aryl iodides, providing the N'-arylated products B.