22611-62-7

Basic information

• Product Name: Bicyclo[2.2.1]heptan-2-amine, N-phenyl-, endo-
• CAS NO: 22611-62-7
• Molecular Formula: C13H17N
• Molecular Weight: 187.285
• Mol File: 22611-62-7.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Bicyclo[2.2.1]heptan-2-amine, N-phenyl-, endo-(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[2.2.1]heptan-2-amine, N-phenyl-, endo-(22611-62-7)
• EPA Substance Registry System: Bicyclo[2.2.1]heptan-2-amine, N-phenyl-, endo-(22611-62-7)

Safety Data

• Hazardous Substances Data: 22611-62-7(Hazardous Substances Data)

Upstream product

• 12082-05-2 (η6-fluorobenzene)tricarbonylchromium 
• 7242-92-4 exo-2-aminonorbornane 
• 279-23-2 norbornene 
• 98-95-3 nitrobenzene 
• 498-66-8 norborn-2-ene 
• 107440-80-2 Ir(PEt₃)2(C₂H₄)2Cl 
• 62-53-3 aniline 
• 39105-82-3 exo-norbornyldichloroborane 
• 622-37-7 Phenyl azide 
• 108-86-1 bromobenzene 

Relevant articles and documents

Inter- and intramolecular hydroamination of unactivated alkenes catalysed by a combination of copper and silver salts: The unveiling of a Bronstedt acid catalysis

The combined use of a copper halide, a silver salt and a phosphane ligand was applied for the catalysis of inter- and intramolecular hydroamination of alkenes. The reactions of unactivated olefins with nitrogen substrates were investigated. Mechanistic investigations demonstrated that the catalytic system generated a Bronsted acid which appeared to be the prominent catalytic species. Copyright

HI-catalyzed hydroamination and hydroarylation of alkenes

Aromatic amines react with alkenes in the presence of catalytic amounts of aqueous HI to give mixtures ef the corresponding hydroamination and hydroarylation products. While the hydroamination reaction is the preferred pathway for aliphatic alkenes, the h

Efficient C-N bond formations catalyzed by a proton-exchanged montmorillonite as a heterogeneous Bronsted acid

Nucleophilic addition of sulfonamides and carboxamides to simple alkenes proceeded smoothly using a proton-exchanged montmorillonite catalyst. The spent catalyst was recovered easily from the reaction mixture and was reusable at least five times without any loss of activity. The unique acidity of the proton-exchanged montmorillonite (H-mont) catalyst was found to be applicable to additional reactions: substitution of hydroxyl groups of alcohols with amides and anilines.