22618-51-5

Basic information

• Product Name: cyclohexen-1-yltoluene
• Synonyms: cyclohexen-1-yltoluene;1-(1-Cyclohexen-1-yl)-2-methylbenzene;1-(2-Methylphenyl)-1-cyclohexene;1-(O-TOLYL)-1-CYCLOHEXENE;1-(cyclohexen-1-yl)-2-methylbenzene
• CAS NO: 22618-51-5
• Molecular Formula: C₁₃H₁₆
• Molecular Weight: 172.26614
• EINECS: 245-131-6
• Mol File: 22618-51-5.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 267.7°Cat760mmHg
• Flash Point: 111.6°C
• Appearance: /
• Density: 0.966g/cm³
• Vapor Pressure: 0.0132mmHg at 25°C
• Refractive Index: 1.547
• CAS DataBase Reference: cyclohexen-1-yltoluene(CAS DataBase Reference)
• NIST Chemistry Reference: cyclohexen-1-yltoluene(22618-51-5)
• EPA Substance Registry System: cyclohexen-1-yltoluene(22618-51-5)

Safety Data

• Hazardous Substances Data: 22618-51-5(Hazardous Substances Data)

Usage

General Description

Cyclohexen-1-yltoluene is a chemical compound with the molecular formula C14H18. It is a derivative of toluene, with a cyclohexene ring attached to the benzene ring. cyclohexen-1-yltoluene is commonly used as an intermediate in the synthesis of various organic compounds, such as pharmaceuticals, agrochemicals, and fragrances. It is also used as a solvent and in the production of polymer resins. Cyclohexen-1-yltoluene is flammable and may cause skin and eye irritation upon contact, so it should be handled with caution and proper safety measures.

InChI:InChI=1/C13H16/c1-11-7-5-6-10-13(11)12-8-3-2-4-9-12/h5-8,10H,2-4,9H2,1H3

Upstream product

• 64-18-6 formic acid 
• 6957-09-1 1-(2-methylphenyl)-1-cyclohexanol 
• 95-46-5 2-methylphenyl bromide 
• 108-94-1 cyclohexanone 
• 932-31-0 ortho-tolylmagnesium bromide 
• 33872-80-9 o-tolyl magnesium chloride 
• 109467-74-5 phosphoric acid cyclohex-1-enyl ester diphenyl ester 
• 7570-92-5 cyclohexyl phenyl sulphide 
• 20474-43-5 bis(1-cyclohexenecarbonyl)peroxide 
• 108-88-3 toluene 
• 930-66-5 1-chlorocyclohexene 
• 68971-87-9 (2-tolyl)tributyltin 
• 615-37-2 ortho-methylphenyl iodide 
• 17497-53-9 1-iodo-1-cyclohexene 

Downstream Products

• 108368-88-3 2-(2-methylphenyl)cyclohex-2-enone 
• 4501-35-3 1-cyclohexyl-2-methylbenzene 
• 643-58-3 2-methylbiphenyl 
• 106269-74-3 1-nitro-2-o-tolyl-cyclohexene 
• 91806-98-3 2-Nitro-1-o-tolyl-cyclohexen-⁽¹⁾-on-⁽⁶⁾-oxim 
• 129353-31-7 1-(2'-Methylphenyl)-7-methylenebicyclo<4.1.0>heptane 
• 93163-07-6 1-Ethoxymethyl-2-o-tolyl-cyclohexen-⁽²⁾ 
• 40656-82-4 (+/-)-cis-2-o-tolyl-cyclohexylamine 
• 93477-15-7 (+/-)-(3-oxo-2t-o-tolyl-cyclohex-t-yl)-acetic acid 
• 63882-42-8 2-(2-methylphenyl)cyclohexanone 
• 92029-21-5 2-Nitro-1-o-tolyl-cyclohexen-⁽¹⁾-on-⁽⁶⁾ 

Relevant articles and documents

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Bimolecular vinylation of arenes by vinyl cations

Styrene derivatives can be easily synthesized from vinyl triflates and arenes under mild reaction conditions, using [Li][Al(OC(CF3)3)4] as a catalyst and LiHMDS as a base. This transformation is likely to involve a vinyl cation intermediate as an electrophile, which is corroborated by DFT calculations, deuterium-labeling and other control experiments. The use of an inert weakly coordinating anion is a decisive factor in this bimolecular vinylation process. This journal is

Single electron transfer-induced cross-coupling reaction of alkenyl halides with aryl Grignard reagents

Alkenyl halides were found to undergo coupling with aryl Grignard reagents to give the corresponding styrene derivatives in a stereo-retained manner. The cross-coupling reaction is considered to proceed through a single electron transfer mechanism.