22628-11-1

Basic information

• Product Name: 2H-Pyran-3-ol, 6-ethenyltetrahydro-2,2,6-trimethyl-, (3S,6S)-
• CAS NO: 22628-11-1
• Molecular Formula: C10H18O2
• Molecular Weight: 170.252
• Mol File: 22628-11-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2H-Pyran-3-ol, 6-ethenyltetrahydro-2,2,6-trimethyl-, (3S,6S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2H-Pyran-3-ol, 6-ethenyltetrahydro-2,2,6-trimethyl-, (3S,6S)-(22628-11-1)
• EPA Substance Registry System: 2H-Pyran-3-ol, 6-ethenyltetrahydro-2,2,6-trimethyl-, (3S,6S)-(22628-11-1)

Safety Data

• Hazardous Substances Data: 22628-11-1(Hazardous Substances Data)

Upstream product

• 126-91-0 linalool 
• 15249-35-1 6,7-epoxylinalool 
• 126-90-9 (S)-(+)-linalool 

Relevant articles and documents

Vanadium(V)-catalyzed oxidation of (3R)-linalool - The selective formation of furanoid linalool oxides and their conversion into isocyclocapitelline derivatives

Oxidation of (3R)-linalool (2) with tert-butyl hydroperoxide (TBHP) occurs at the 6,7-position to selectively afford linalool oxide cis-1, if catalyzed by vanadium(V) Schiff base complexes 4. Substituted tetrahydrofuran cis-1 and its isomer trans-1 served

Rearrangements of epoxides of linalool and nerolidyl acetate in acid media

The behavior of epoxides of linalool and cis-nerolidyl acetate was comparatively investigated in acids of various strength with the goal of establishing the effect of the structure of the initial compound and the medium character on the main direction of cationoid rearrangement. Linalool epoxides undergo cyclization of solid acid catalysts affording oxygen-containing heterocyclic compounds whereas the nerolidyl acetate epoxides yield the ketones originating from the opening of the epoxy ring followed by 1,2-hydride shift. 10,11-Epoxy derivative of cis-nerolidyl acetate affords 7-oxanorbornane as a minor product.