22632-90-2

Basic information

• Product Name: Benzenemethanimine, 4-methyl-a-phenyl-
• Synonyms: Phenyl-p-tolylketimin;C-Phenyl-C-p-tolyl-methyleneamine;4-methylbenzophenone imine;p-tolylphenylketimine;4-Methyl-benzophenonimin;Phenyl-p-tolyl-ketimid;4-Methyl-benzophenon-imin
• CAS NO: 22632-90-2
• Molecular Formula: C14H13N
• Molecular Weight: 195.264
• Mol File: 22632-90-2.mol
• Article Data: 5

Chemical Properties

• Melting Point: 37 °C
• Boiling Point: 91 °C (0.04 mmHg)
• Density: 1.0617 g/cm3
• CAS DataBase Reference: Benzenemethanimine, 4-methyl-a-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanimine, 4-methyl-a-phenyl-(22632-90-2)
• EPA Substance Registry System: Benzenemethanimine, 4-methyl-a-phenyl-(22632-90-2)

Safety Data

• Hazardous Substances Data: 22632-90-2(Hazardous Substances Data)

Upstream product

• 106-38-7 para-bromotoluene 
• 100-47-0 benzonitrile 
• 591-51-5 phenyllithium 
• 104-85-8 para-methylbenzonitrile 
• 17234-63-8 2,2-dimethyl-1-phenyl-hexan-1-one 
• 108-86-1 bromobenzene 
• 4294-57-9 para-methylphenylmagnesium bromide 
• 588-64-7 benzaldehyde phenylhydrazone 
• 56-23-5 tetrachloromethane 

Downstream Products

• 26404-41-1 C₁₈H₁₇Cl₃N₂O 
• 25924-56-5 (2,2,2-Trichloro-1-{[1-phenyl-1-p-tolyl-meth-(Z)-ylidene]-amino}-ethyl)-phosphoramidic acid diethyl ester 
• 143678-00-6 2-p-tolyl-2,4,5-triphenyl-2H-imidazole N-oxide 
• 119208-57-0 α-Methoxy-4-nitro-N-(phenyl-p-tolylmethylen)benzylamin 
• 72670-79-2 phenyl(p-tolyl)methaniminium chloride 
• 51250-41-0 Chlorphenyl-p-tolyl-methylisocyanat 
• 134-84-9 4-Methylbenzophenone 
• 110900-29-3 WOF₄NC(C₆H₅)(C₆H₄CH₃)^(1-) 
• 143678-11-9 1,3-diaza-6-oxa-2-p-tolyl-2,4,5-triphenylbicyclo<3.1.0>hex-3-ene 
• 143678-15-3 2-p-tolyl-2,4,5-triphenyl-2H-imidazole 
• 143678-07-3 1,3-diaza-4,5-dimethyl-6-oxa-2-phenyl-2-p-tolylbicyclo<3.1.0>hex-3-ene 
• 143678-14-2 4,5-dimethyl-2-phenyl-2-p-tolyl-2H-imidazole 
• 125367-66-0 N-[(phenyl)(p-tolyl)methylene]aniline 
• 55095-21-1 phenyl-p-tolylmethylamine 

Relevant articles and documents

Light-Driven Enantioselective Synthesis of Pyrroline Derivatives by a Radical/Polar Cascade Reaction

Herein, a light-driven, atom-economical process that provides access to enantiomerically enriched substituted chiral 1-pyrroline derivatives is introduced. The strategy involves the distal functionalization of acyl heterocycles through a hydrogen-atom transfer (HAT) process and the use of tailor-made ketimines as reliable electrophilic partners. This transformation is translated into an enantiomerically controlled radical/polar cascade reaction in which water is produced as the sole by-product and stereoselectivity is dictated by coordination to a chiral-at-rhodium catalyst.

Hydrogen bond directed aerobic oxidation of amines via photoredox catalysis

An application of H-bonding interactions for directing the α-C-H oxidation of amines to amides and amino-ketones catalyzed by an organic photocatalyst is reported. The high efficiency of this method is demonstrated by the aerobic oxidation of pyrrolidines, diarylamines and benzylamines bearing urea groups with high yields and a wide substrate scope.

Synthesis of substituted benzhydrylamines

The synthesis of para di- and monosubstituted benzhydrylamines by addition of Grignard reagents to benzonitriles and subsequent reduction, is evaluated and discussed. The reduction step with sodium borohydride allows simple handling and mild conditions. An optimized synthesis of 4,4'-dimethoxybenzhydrylamine by this method is disclosed.