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2269-22-9 Usage

Description

Aluminium tri-sec-butoxide, also known as tri-sec-butyl aluminum, is a chemical compound with the formula (C4H9)3AlO. It is a viscous, colorless, or pale yellow liquid that exhibits unique chemical properties, making it suitable for various applications across different industries.

Uses

Used in the Chemical Industry:
Aluminium tri-sec-butoxide is used as an active catalyst and support for various chemical reactions due to its ability to facilitate and enhance the reaction rates.
Used in the Membrane Industry:
It is utilized as an inorganic membrane, providing a stable and durable barrier for various applications, such as gas separation and filtration processes.
Used in the Pharmaceutical Industry:
Aluminium tri-sec-butoxide serves as a reducing agent for aldehyde-ketone compounds, playing a crucial role in the synthesis of various pharmaceutical products.
Used in the Oxidation Process:
It acts as an oxidant for aldehyde-ketone compounds, enabling the controlled oxidation of these substances in chemical reactions.
Used in the Printing and Paint Industry:
Aluminium tri-sec-butoxide is employed as a gel-forming agent in the production of printing inks and paints, contributing to their viscosity and stability.
Used in the Dehydration Process:
It functions as a dehydrant, helping to remove moisture from various substances and processes, which is essential for maintaining product quality and preventing spoilage.
Used in the Waterproofing Industry:
Aluminium tri-sec-butoxide is used as a waterproofing agent, providing a protective barrier against water and moisture, making it ideal for applications in construction and coatings.
Used in the Lubricant Industry:
It is utilized as a component in the formulation of aluminum base grease, enhancing the lubricating properties and performance of the final product.

Flammability and Explosibility

Flammable

Check Digit Verification of cas no

The CAS Registry Mumber 2269-22-9 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,2,6 and 9 respectively; the second part has 2 digits, 2 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 2269-22:
(6*2)+(5*2)+(4*6)+(3*9)+(2*2)+(1*2)=79
79 % 10 = 9
So 2269-22-9 is a valid CAS Registry Number.
InChI:InChI=1/C4H10O.Al/c1-3-4(2)5;/h4-5H,3H2,1-2H3;/q;+3

2269-22-9 Well-known Company Product Price

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  • Detail
  • Alfa Aesar

  • (30721)  Aluminum sec-butoxide, 95%   

  • 2269-22-9

  • 10g

  • 153.0CNY

  • Detail
  • Alfa Aesar

  • (30721)  Aluminum sec-butoxide, 95%   

  • 2269-22-9

  • 100g

  • 361.0CNY

  • Detail
  • Alfa Aesar

  • (30721)  Aluminum sec-butoxide, 95%   

  • 2269-22-9

  • 500g

  • 574.0CNY

  • Detail
  • Alfa Aesar

  • (30721)  Aluminum sec-butoxide, 95%   

  • 2269-22-9

  • *4x500g

  • 767.0CNY

  • Detail
  • Alfa Aesar

  • (43712)  Aluminum sec-butoxide, 95%, packaged under Argon in resealable ChemSeal? bottles   

  • 2269-22-9

  • 100g

  • 387.0CNY

  • Detail
  • Alfa Aesar

  • (43712)  Aluminum sec-butoxide, 95%, packaged under Argon in resealable ChemSeal? bottles   

  • 2269-22-9

  • 500g

  • 629.0CNY

  • Detail
  • Alfa Aesar

  • (A13044)  Aluminum sec-butoxide, 97%   

  • 2269-22-9

  • 100g

  • 345.0CNY

  • Detail
  • Alfa Aesar

  • (A13044)  Aluminum sec-butoxide, 97%   

  • 2269-22-9

  • 500g

  • 700.0CNY

  • Detail
  • Alfa Aesar

  • (A13044)  Aluminum sec-butoxide, 97%   

  • 2269-22-9

  • 2500g

  • 3126.0CNY

  • Detail
  • Aldrich

  • (511609)  Aluminum-tri-sec-butoxide  99.99% trace metals basis

  • 2269-22-9

  • 511609-5G

  • 1,648.53CNY

  • Detail
  • Aldrich

  • (201073)  Aluminum-tri-sec-butoxide  97%

  • 2269-22-9

  • 201073-100G

  • 607.23CNY

  • Detail
  • Aldrich

  • (201073)  Aluminum-tri-sec-butoxide  97%

  • 2269-22-9

  • 201073-500G

  • 981.63CNY

  • Detail

2269-22-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name Aluminium tri-sec-butoxide

1.2 Other means of identification

Product number -
Other names ALUMINUM SEC-BUTOXIDE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:2269-22-9 SDS

2269-22-9Synthetic route

sec-butyl formate
589-40-2

sec-butyl formate

aluminum isopropoxide
555-31-7

aluminum isopropoxide

A

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

B

isopropyl formate

isopropyl formate

amalgamated aluminium

amalgamated aluminium

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

aluminum isopropoxide
555-31-7

aluminum isopropoxide

sec-butyl formate

sec-butyl formate

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

Conditions
ConditionsYield
unter Abdestillieren von Isopropylformiat;
aluminium
7429-90-5

aluminium

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

Conditions
ConditionsYield
In neat (no solvent) treatment of the metal with alcohol in the presence of HgCl2 or I2 as catalysts; identified by elem. anal. for Al and by comparison of the constants withpublished data;
formic acid
64-18-6

formic acid

water
7732-18-5

water

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

aluminium triformate trihydrate

aluminium triformate trihydrate

Conditions
ConditionsYield
In water addn. of water to Al(CH3CHOC2H5)3 (air), formation of hydroxide, addn. of formic acid and water, boiling and evapn., keeping at 60°C till complete evapn., drying (2 d over drierite); TGA, DTA;100%
aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

acetylacetone
123-54-6

acetylacetone

aluminium(III) acetylacetonate

aluminium(III) acetylacetonate

Conditions
ConditionsYield
In ethanol at 0℃;97%
1-(4,4-dimethyl-4,5-dihydrooxazol-2-yl)naphthalen-2-ol
1337458-59-9

1-(4,4-dimethyl-4,5-dihydrooxazol-2-yl)naphthalen-2-ol

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

mer-[Al(1-(4,4-dimethyl-4,5-dihydrooxazol-2-yl)naphthalen-2-olate)3]

mer-[Al(1-(4,4-dimethyl-4,5-dihydrooxazol-2-yl)naphthalen-2-olate)3]

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 1h; Inert atmosphere; Schlenk technique;95%
carbon monoxide
201230-82-2

carbon monoxide

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

2-bromomethylnaphthyl bromide
939-26-4

2-bromomethylnaphthyl bromide

Naphthalen-2-yl-acetic acid sec-butyl ester
91759-49-8

Naphthalen-2-yl-acetic acid sec-butyl ester

Conditions
ConditionsYield
1,5-hexadienerhodium(I)-chloride dimer In n-heptane at 75℃; for 14h;91%
3-methyl-1-butyl acetate
123-92-2

3-methyl-1-butyl acetate

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

aluminium triisopentylate
25016-92-6

aluminium triisopentylate

Conditions
ConditionsYield
In neat (no solvent) byproducts: sec-Bu-OAc; N2 atmosphere; exchange reaction (111°C); distn. of butyl ester;90%
aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

magnesium
7439-95-4

magnesium

Mg{Al(OCH(CH3)CH2CH3)4}2

Mg{Al(OCH(CH3)CH2CH3)4}2

Conditions
ConditionsYield
With Hg2Cl2 In butan-1-ol byproducts: H2; under N2; addn. of Mg turnings and Hg2Cl2 to stirred soln. of 2 equiv. of Al(O-sec-Bu)3 in sec-butanol, refluxed (7 d); evapn. (vac.), fractional distn. at 140-165°C/0.03 Torr, elem. anal.;86%
water
7732-18-5

water

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

alumina

alumina

Conditions
ConditionsYield
Stage #1: water; aluminum tri-sec-butoxide With ammonium hydroxide In ethanol; iso-butanol at 70℃; for 25h;
Stage #2: at 400℃; for 10h; Calcination;
82%
1,2-bis[2-(4,4,4-trifluoro-1-hydroxy-3-oxobut-1-enyl)phenoxy]ethane

1,2-bis[2-(4,4,4-trifluoro-1-hydroxy-3-oxobut-1-enyl)phenoxy]ethane

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

[Al2(1,2-bis[2-(4,4,4-trifluoro-1-hydroxy-3-oxobut-1-enyl)phenoxy]ethane)3]

[Al2(1,2-bis[2-(4,4,4-trifluoro-1-hydroxy-3-oxobut-1-enyl)phenoxy]ethane)3]

Conditions
ConditionsYield
In hexane; chloroform for 72h;75%
aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

methyl iodide
74-88-4

methyl iodide

2-butyl methyl ether
6795-87-5

2-butyl methyl ether

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 59 - 70℃; for 48h;70%
carbon monoxide
201230-82-2

carbon monoxide

benzyl bromide
100-39-0

benzyl bromide

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

phenyl-acetic acid sec-butyl ester
5436-58-8

phenyl-acetic acid sec-butyl ester

Conditions
ConditionsYield
1,5-hexadienerhodium(I)-chloride dimer In n-heptane at 75℃; for 14h;68%
2-[(S)-4-isopropyl-4,5-dihydro-oxazol-2-yl]-6-methylphenol
1104058-34-5

2-[(S)-4-isopropyl-4,5-dihydro-oxazol-2-yl]-6-methylphenol

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

mer-[Al((S)-2-(4-isopropyl-4,5-dihydrooxazol-2-yl)-6-methylphenolate)3]

mer-[Al((S)-2-(4-isopropyl-4,5-dihydrooxazol-2-yl)-6-methylphenolate)3]

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 1h; Inert atmosphere; Schlenk technique;40%
titanium(IV) isopropylate
546-68-9

titanium(IV) isopropylate

calcium(II) nitrate tetrahydrate

calcium(II) nitrate tetrahydrate

hafnium tetra(n-butoxide)
876504-21-1

hafnium tetra(n-butoxide)

gadolinium(III) nitrate hexahydrate

gadolinium(III) nitrate hexahydrate

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

A

Al1.96Ti1.02O5

Al1.96Ti1.02O5

B

Ca0.25Gd0.77Hf0.06Al0.65Ti2.26O7

Ca0.25Gd0.77Hf0.06Al0.65Ti2.26O7

C

(Ca0.12Hf0.06Al0.09Gd1.73)Ti2.02O7

(Ca0.12Hf0.06Al0.09Gd1.73)Ti2.02O7

Conditions
ConditionsYield
In ethanol; water Ti and Hf alkoxides in EtOH and Ca and Gd nitrates (Ca:Gd:Hf:Al:Ti=0.1:1.5:0.1:0.3:1.85) in H2O mixed for 15 min; dried; calcined at 700°C for 1 h; ball milled for 18 h in water; pelletized at 30 MPa; sinteredin air (1500°C, 96 h); detd. by energy dispersive X-ray spectrometry and X-ray diffraction;A n/a
B 2%
C n/a
titanium(IV) isopropylate
546-68-9

titanium(IV) isopropylate

calcium(II) nitrate tetrahydrate

calcium(II) nitrate tetrahydrate

hafnium tetra(n-butoxide)
876504-21-1

hafnium tetra(n-butoxide)

gadolinium(III) nitrate hexahydrate

gadolinium(III) nitrate hexahydrate

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

A

Al2.02Gd0.01Ti0.97O5

Al2.02Gd0.01Ti0.97O5

B

(Ca0.19Hf0.16Al0.09Gd1.59)Ti2.00O7

(Ca0.19Hf0.16Al0.09Gd1.59)Ti2.00O7

C

Ca0.16Gd0.87Hf0.04Al0.93Ti4.00O11

Ca0.16Gd0.87Hf0.04Al0.93Ti4.00O11

Conditions
ConditionsYield
In ethanol; water Ti and Hf alkoxides in EtOH and Ca and Gd nitrates (Ca:Gd:Hf:Al:Ti=0.2:1.4:0.2:0.2:1.9) in H2O mixed for 15 min; dried; calcined at 700°Cfor 1 h; ball milled for 18 h in water; pelletized at 30 MPa; sintered in air (1500°C, 96 h); detd. by energy dispersive X-ray spectrometry and X-ray diffraction;A n/a
B n/a
C 2%
lauric acid
143-07-7

lauric acid

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

lauric acid ; aluminium-hydroxide-dil aurate

lauric acid ; aluminium-hydroxide-dil aurate

4-methyl-pent-3-en-2-one
141-79-7

4-methyl-pent-3-en-2-one

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

A

4-methyl pent-3-en-2-ol
4325-82-0

4-methyl pent-3-en-2-ol

B

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

C

1,3-Dimethyl-1,3-butadien
1118-58-7

1,3-Dimethyl-1,3-butadien

9-fluorenone
486-25-9

9-fluorenone

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

9-Fluorenol
1689-64-1

9-Fluorenol

Conditions
ConditionsYield
at 105 - 110℃;
cis-Octadecenoic acid
112-80-1

cis-Octadecenoic acid

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

oleic acid ; aluminium dioleate

oleic acid ; aluminium dioleate

Conditions
ConditionsYield
With 1,4-dioxane
With butan-1-ol
With benzene
3-nitro-benzaldehyde
99-61-6

3-nitro-benzaldehyde

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

3-Nitrobenzyl alcohol
619-25-0

3-Nitrobenzyl alcohol

4-nitrobenzaldehdye
555-16-8

4-nitrobenzaldehdye

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

4-nitrobenzyl chloride
619-73-8

4-nitrobenzyl chloride

Conditions
ConditionsYield
With iso-butanol
4-nitrobenzaldehdye
555-16-8

4-nitrobenzaldehdye

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

4-nitrobenzyl chloride
619-73-8

4-nitrobenzyl chloride

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

(E)-benzalacetone
1896-62-4

(E)-benzalacetone

ethyl (E)-1-phenylbut-1-en-3-ol
36004-04-3

ethyl (E)-1-phenylbut-1-en-3-ol

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

2-nitro-benzaldehyde
552-89-6

2-nitro-benzaldehyde

2-Nitrobenzyl alcohol
612-25-9

2-Nitrobenzyl alcohol

Conditions
ConditionsYield
With iso-butanol
aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

2-nitro-benzaldehyde
552-89-6

2-nitro-benzaldehyde

2-Nitrobenzyl alcohol
612-25-9

2-Nitrobenzyl alcohol

9-fluorenone
486-25-9

9-fluorenone

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

9-Fluorenol
1689-64-1

9-Fluorenol

(2R,5S)-menthone
10458-14-7, 14073-97-3

(2R,5S)-menthone

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

A

(-)-menthol
2216-51-5

(-)-menthol

B

Neomenthol
2216-52-6

Neomenthol

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

1-Naphthyl isocyanate
86-84-0

1-Naphthyl isocyanate

N-<1>Naphthylcarbamoyl-<1>naphthylcarbamidsaeure-sec-butylester
6229-90-9

N-<1>Naphthylcarbamoyl-<1>naphthylcarbamidsaeure-sec-butylester

2,3-epoxy-2-methylpropionaldehyde
161111-61-1

2,3-epoxy-2-methylpropionaldehyde

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

1-methylpropyl-2,3-epoxy-2-methylpropanoate

1-methylpropyl-2,3-epoxy-2-methylpropanoate

Conditions
ConditionsYield
In benzene at 20℃; for 120h;2.9 g
2,3-epoxy-2-methylpropionaldehyde
161111-61-1

2,3-epoxy-2-methylpropionaldehyde

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

α-methyl-α-(1-sec-butoxy-2-methyl-2,3-epoxypropyloxy)-β-propiolactone

α-methyl-α-(1-sec-butoxy-2-methyl-2,3-epoxypropyloxy)-β-propiolactone

Conditions
ConditionsYield
In benzene at 20℃; for 120h;
1,4-dioxane
123-91-1

1,4-dioxane

cis-Octadecenoic acid
112-80-1

cis-Octadecenoic acid

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

aluminium oleate/s

aluminium oleate/s

cis-Octadecenoic acid
112-80-1

cis-Octadecenoic acid

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

aluminium oleate/s

aluminium oleate/s

2269-22-9Relevant articles and documents

Thermolysis of alkoxyaluminum and siloxyaluminum acylates

Stepovik,Kazakina,Martynova

, p. 1371 - 1377 (2007/10/03)

Thermolysis of alkoxyaluminum acylates (RO)nAl(OCORt)3-n (n = 1, 2; R = i-Pr, s-Bu, t-Bu, Rt = Ph, CH2I; R = PhCH2, Rt = Me, Et, Ph; R = Me3Si, Et3Si, Rt = Me) was studied. The main direction of thermolysis of derivatives of primary and secondary alcohols and of unsubstituted carboxylic acids is ester and alcohol formation. Trialkylsiloxyaluminum acylates termolyze to give in the first stage no other products than trialkylacyloxysilanes. Thermolysis of iodoacylates (RO)2AlOCOCH2I (R = Pr, s-Bu) involves oxidation of the alkoxy group to carbonyl compounds with simultaneous formation of a ketene and hydrogen iodide. tert-Butoxyaluminum acylates regardless of the structure of substituent in the acyloxy group undergo symmetrization to aluminum tert-butylate.

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