22846-16-8Relevant articles and documents
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Chan et al.
, p. 1097 (1969)
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A new stereoselective synthesis of phosphiranes
Li, Xinhua,Robinson, Kerry D.,Gaspar, Peter P.
, p. 7702 - 7710 (1996)
The synthesis of phosphiranes from primary phosphines and diol ditosylates was found to be stereoselective, and chiral phosphiranes were prepared from optically pure diols. The four optical isomers of 1-mesityl-2,3-dimethylphosphirane, (2S,3S)-(+)-3, (2R,3R)-(-)-4, anti-cis-(meso)-5, and syn-cis-(meso)-6, were all synthesized from mesitylphosphine and the corresponding diol ditosylates. Compound 6 was unstable, but compounds 3, 4, and 5 were all isolated in pure form. Their structure assignments were based on the NMR coupling constants JP-H and JP-C. The phosphiranes were transformed into tungsten pentacarbonyl complexes. Tungsten tetracarbonyl-triphenylphosphine complexes (22, 23, 24) of compounds 3, 4, and 5 were synthesized in high yields by the reaction of the phosphiranes and W(CO)4(PPh3)(THF). The absolute stereochemistry of the phosphiranes 3, 4, and 5 was determined by X-ray crystal structure analysis of compounds 22, 23, and 24. Stereochemical effects on NMR coupling constants and mass spectra of the phosphiranes are discussed.
Direct Syntheses of 1-Phenylphosphetane and 1-Phenylphosphirane. Crystal and Molecular Structures of Cyclotrimerisation Precursor Complexes and
Kang, Yew Beng,Pabel, Michael,Willis, Anthony C.,Wild, S. Bruce
, p. 475 - 476 (2007/10/02)
Dilithium phenylphosphide reacts with 1,3-dichloropropane or 1,2-dichloroethane to give 1-phenylphosphetane or 1-phenylphosphirane, respectively; the free phosphines have been used to prepare the cyclotrimerisation precursor complexes and formu