22875-82-7

Basic information

• Product Name: Benzeneacetaldehyde, a-methyl-a-phenyl-
• Synonyms: 2,2-diphenyl propanal;2.2-Diphenyl-propanal-(1);1-Oxo-2.2-diphenyl-propan;2,2-diphenylpropionaldehyde;2,2-diphenyl-propionaldehyde;2,2-Diphenyl-propionaldehyd
• CAS NO: 22875-82-7
• Molecular Formula: C15H14O
• Molecular Weight: 210.276
• Mol File: 22875-82-7.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: Benzeneacetaldehyde, a-methyl-a-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneacetaldehyde, a-methyl-a-phenyl-(22875-82-7)
• EPA Substance Registry System: Benzeneacetaldehyde, a-methyl-a-phenyl-(22875-82-7)

Safety Data

• Hazardous Substances Data: 22875-82-7(Hazardous Substances Data)

Upstream product

• 10282-18-5 α-methylstilbene oxide 
• 41728-16-9 1,2-diphenylpropan-1,2-diol 
• 1084-78-2 (1RS,2SR)-(+/-)-1,2-diphenyl-1,2-propandiol 
• 144-62-7 oxalic acid 
• 13733-16-9 threo-2-Hydroxy-1-acetoxy-1,2-diphenyl-propan 
• 13733-16-9 erythro-1,2-Dihydroxy-1,2-diphenyl-propan-1-acetat 
• 71-43-2 benzene 
• 833-81-8 (E)-1,2-diphenylpropene 
• 1084-78-2 (1RS,2RS)-(+/-)-1,2-diphenyl-1,2-propandiol 
• 40997-78-2 2,2-diphenylpropionyl chloride 
• 5558-66-7 2,2-diphenylpropanoic acid 
• 10282-18-5 trans-2,3-diphenyl-2-methyl oxirane 
• 7664-93-9 sulfuric acid 
• 530-48-3 1,1-Diphenylethylene 

Downstream Products

• 22875-81-6 3,3-diphenyl-butan-2-ol 
• 74421-26-4 2,2-diphenylpropan-1-ol 
• 1026802-09-4 3-Oxo-4,4-diphenyl-pentanoic acid methoxycarbonylmethyl ester 
• 117918-91-9 methyl (E)-2-cyano-4,4-diphenyl-2-pentenoate 
• 197971-84-9 2-hydroxy-3,3-diphenylbutyronitrile 
• 187335-03-1 2-dimethylamino-3,3-diphenylbutyronitrile 
• 2042-85-5 1,2-diphenylpropan-1-one 
• 5558-66-7 2,2-diphenylpropanoic acid 
• 117919-02-5 cis-4-cyano-5-(1,1-diphenylethyl)-4-(methoxycarbonyl)-3-methyl-3-(p-methylphenyl)-1-pyrazoline 
• 117919-01-4 cis-4-cyano-5-(1,1-diphenylethyl)-4-(methoxycarbonyl)-3-methyl-3-(p-chlorophenyl)-1-pyrazoline 
• 117918-93-1 cis-4-cyano-4-(methoxycarbonyl)-3-methyl-3-phenyl-5-(1,1-diphenylethyl)-1-pyrazoline 
• 117918-93-1 trans-4-cyano-4-(methoxycarbonyl)-3-methyl-3-phenyl-5-(1,1-diphenylethyl)-1-pyrazoline 
• 33498-62-3 9-methyl-10-phenylphenanthrene 
• 1139694-63-5 1-(1,1-diphenylethyl)prop-2-yn-1-yl acetate 

Relevant articles and documents

New synthetic route to pharmacologically active 1-(N,N-dialkylamino)-3,3-diarylpropanes via rhodium-catalyzed hydroformylation of 1,1-diarylethenes

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Mild Iridium-Catalysed Isomerization of Epoxides. Computational Insights and Application to the Synthesis of β-Alkyl Amines

The isomerization of epoxides to aldehydes using the readily available Crabtree's reagent is described. The aldehydes were transformed into synthetically useful amines by a one-pot reductive amination using pyrrolidine as imine-formation catalyst. The reactions worked with low catalyst loadings in very mild conditions. The procedure is operationally simple and tolerates a wide range of functional groups. A DFT study of its mechanism is presented showing that the isomerization takes place via an iridium hydride mechanism with a low energy barrier, in agreement with the mild reaction conditions. (Figure presented.).

Catalytic Asymmetric Formal Insertion of Aryldiazoalkanes into the C-H Bond of Aldehydes: Synthesis of Enantioenriched Acyclic α-Tertiary Aryl Ketones

A novel, catalytic enantioselective route to synthesize a variety of α-tertiary aryl ketones via a boron Lewis acid promoted formal insertion of aryldiazoalkane into the C-H bond of both aromatic and aliphatic aldehydes is described. In the presence of ch