2288-38-2Relevant articles and documents
Solvent effects on hydride transfer from Cp?(P-P)FeH to BNA+ cation
Zhang, Fanjun,Xu, Xin,Zhao, Yingjie,Jia, Jiong,Tung, Chen-Ho,Wang, Wenguang
, p. 1238 - 1244 (2017)
Examining of the hydride transfer reaction between Cp?(Ph2PNtBuPPh2)-FeH (Ph2PNtBuPPh2 = N,N-bis(diphenylphosphanyl)tert-butylamine, 1-H) and 1-benzyl-3-carbamoylpyridinium cation (BNA+) in different solvents, we found that the solvents exert considerable influence on the hydride transfer processes. A coordinating solvent molecule such as MeCN is not only a ligand which stabilizes the organo-iron fragment producing [Cp?(Ph2PNtBuPPh2)Fe(NCMe)]+ ([1(NCMe)]+), but also assists the hydride transfer. In THF, reaction of 1-H with BNA+ under high pressure of nitrogen (60 psi) giving the iron(II)-nitrogen complex [Cp?(Ph2PNtBuPPh2)Fe(N2)]+ ([1-N2]+) and BNAH. In CH2Cl2, [1-N2]+ catalyzes the conversion of 1-H to Cp?(Ph2PNtBuPPh2)- FeCl (1-Cl), which hampers the expected hydride transfer reaction. In the presence of MeCN, the hydride transfer process in THF, CH2Cl2, or benzene was achieved affording the reduced BNAH and [1(NCMe)]+. New iron complexes in the [Cp?(Ph2PNtBuPPh2)-FeX]n+ series (where n = 0, X = H or Cl; n = 1, X = MeCN, N2, or Cl-) were obtained and well characterized.
A Novel Type of Hydride-transfer Photocatalysis by RuII-Pyridine Complexes: Regiocontrolled Reduction of an NAD(P) Model Compound by Triethylamine
Ishitani, Osamu,Inoue, Nobuyo,Koike, Kazuhide,Ibusuki, Takashi
, p. 367 - 368 (1994)
2+ (trpy = 2,2':6',2''-terpyridine, bpy = 2,2'-bipyridine, py = pyridine) and 2+ (LL = abidendate ligand) photocatalysed the regiocontrolled reduction of 1-benzyl-4-carbamoyle-pyridinium cation to the
Regioselective reduction of NAD+ models with [Cp*Rh(bpy)H]+: Structure-activity relationships and mechanistic aspects in the formation of the 1,4-NADH derivatives
Lo, H. Christine,Buriez, Olivier,Kerr, John B.,Fish, Richard H.
, p. 1429 - 1432 (2007/10/03)
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