22882-91-3

Basic information

• Product Name: (E)-1-ethoxy-3,7-dimethylocta-2,6-diene
• Synonyms: (E)-1-ethoxy-3,7-dimethylocta-2,6-diene;6-Octadiene, 1-ethoxy-3,7-dimethyl-, (E)-2;(2E)-1-Ethoxy-3,7-dimethyl-2,6-octadiene;2,6-Octadiene, 1-ethoxy-3,7-dimethyl-, (2E)-;2,6-Octadiene, 1-ethoxy-3,7-dimethyl-, (E)-;Einecs 245-288-0;trans-3,7-Dimethyl-2,6-octadienyl ethyl ether
• CAS NO: 22882-91-3
• Molecular Formula: C₁₂H₂₂O
• Molecular Weight: 182.30248
• EINECS: 245-288-0
• Mol File: 22882-91-3.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 240.2±19.0 °C(Predicted)
• Appearance: /
• Density: 0.829±0.06 g/cm3(Predicted)
• CAS DataBase Reference: (E)-1-ethoxy-3,7-dimethylocta-2,6-diene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-ethoxy-3,7-dimethylocta-2,6-diene(22882-91-3)
• EPA Substance Registry System: (E)-1-ethoxy-3,7-dimethylocta-2,6-diene(22882-91-3)

Safety Data

• Hazardous Substances Data: 22882-91-3(Hazardous Substances Data)

Usage

General Description

(E)-1-ethoxy-3,7-dimethylocta-2,6-diene, also known as Ethyl geranyl ether, is a chemical compound commonly found in various essential oils. It is a colorless liquid with a floral, fruity odor, and is used in the production of perfumes and flavorings. It is also known for its insecticidal and antimicrobial properties, making it a common ingredient in household and agricultural pesticides. Ethyl geranyl ether is produced through the reaction of geraniol with ethyl alcohol, and it is considered to be relatively safe for human and environmental health when used in controlled concentrations.

Upstream product

• 4490-10-2 geranyl chloride 
• 64-17-5 ethanol 
• 6138-90-5 geranyl bromide 
• 32659-10-2 (E)-1-bromo-4-ethoxy-2-methyl-but-2-ene 
• 870-63-3 prenyl bromide 
• 75-03-6 ethyl iodide 
• 78055-70-6 trimethyl[(E)-3,7-dimethylocta-2,6-dienyl]silane 
• 74589-92-7 linalyl carbonate 
• 4648-54-8 trimethylsilylazide 
• 74-96-4 ethyl bromide 
• 106-24-1 Geraniol 
• 78-39-7 Triethyl orthoacetate 
• 78-70-6 3,7-dimethylocta-1,6-dien-3-ol 
• 126-91-0 linalool 

Downstream Products

• 141-27-5 3,7-dimethyl-2,6-octadienal 
• 106-24-1 Geraniol 

Relevant articles and documents

Asymmetric Traceless Petasis Borono-Mannich Reactions of Enals: Reductive Transposition of Allylic Diazenes

The traceless Petasis borono-Mannich reaction of enals, sulfonylhydrazines, and allylboronates, catalyzed by chiral biphenols, results in an asymmetric reductive transposition of the in situ generated allylic diazene. Acyclic 1,4-diene products bearing either alkyl- or aryl-substituted benzylic stereocenters are afforded in excellent yields and enantiomeric ratios of up to 99:1. The use of crotylboronates in the reaction results in concomitant formation of two stereocenters in either a 1,4-syn or anti relationship from the corresponding E- or Z-crotylboronate used in the reaction. The use of β-monosubstituted enals in the asymmetric traceless Petasis borono-Mannich reaction of crotylboronates installs tertiary methyl-bearing stereocenters in good yields and high enantioselectivities.

PALLADIUM(0)-CATALYZED AZIDATION OF ALLYL ESTERS WITH TRIMETHYLSILYL AZIDE

Palladium(0)-catalyzed reaction of allyl esters with trimethylsilyl azide gives, under anhydrous conditions, the corresponding allyl azides.