22883-69-8

Basic information

• Product Name: Benzyl-tris-(4-dimethylamino-phenyl)-phosphonium; bromide
• Synonyms: Benzyl-tris-(4-dimethylamino-phenyl)-phosphonium; bromide
• CAS NO: 22883-69-8
• Molecular Weight: 562.533
• Mol File: 22883-69-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzyl-tris-(4-dimethylamino-phenyl)-phosphonium; bromide(CAS DataBase Reference)
• NIST Chemistry Reference: Benzyl-tris-(4-dimethylamino-phenyl)-phosphonium; bromide(22883-69-8)
• EPA Substance Registry System: Benzyl-tris-(4-dimethylamino-phenyl)-phosphonium; bromide(22883-69-8)

Safety Data

• Hazardous Substances Data: 22883-69-8(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 1104-21-8 tris(p-dimethylaminophenyl)phosphine 

Downstream Products

• 54624-34-9 (4-methylpent-1-en-1-yl)benzene 
• 15325-61-8 3-methyl-1-phenyl-1-butene 
• 3412-44-0 1,3-diphenylpropene 
• 588-59-0 stilbene 
• 864078-99-9 C₃₁H₃₆N₃P 

Relevant articles and documents

Untersuchungen im Wittig-System nach einem ordnenden Konzept auf der Basis alternativer Prinzipien

Our results show that the stereoselectivity of the Wittig-reaction can be controlled by the variation of substituents in accord with the ORDERING CONCEPT OF ALTERNATIV PRINCIPLES (individual pairs, known and unknown classes of alternatives).The "all-phenyl Wittig-system" having three phenyl groups on phosphorous two in ylid- and aldehyd-position was chosen as a standard for our investigations.Differentiation in ylid-position and compensation on phosphorous and aldehyd-position were observed by the comparison of "patterns".Consequently, most of the selectivity rules of Wittig-reactions can be explained by the differentiation through alternatives in the ylid-position.Inversion or conservation of the "patterns" of measured data points to the variation in structure of starting materials, reaction rates and selectivities.Amount-controls were also described in certain systems.