2296-13-1

Basic information

• Product Name: N-hexylhexan-1-amine hydrochloride (1:1)
• Synonyms: 1-hexanamine, N-hexyl-, hydrochloride (1:1); Di-n-hexylammonium chloride; Hexanamine, n-hexyl-, hydrochloride; N-Hexylhexan-1-amine hydrochloride (1:1)
• CAS NO: 2296-13-1
• Molecular Formula: C₁₂H₂₈ClN
• Molecular Weight: 221.8104
• Mol File: 2296-13-1.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 193.5°C at 760 mmHg
• Flash Point: 95°C
• Vapor Pressure: 0.463mmHg at 25°C
• CAS DataBase Reference: N-hexylhexan-1-amine hydrochloride (1:1)(CAS DataBase Reference)
• NIST Chemistry Reference: N-hexylhexan-1-amine hydrochloride (1:1)(2296-13-1)
• EPA Substance Registry System: N-hexylhexan-1-amine hydrochloride (1:1)(2296-13-1)

Safety Data

• Hazardous Substances Data: 2296-13-1(Hazardous Substances Data)

Upstream product

• 18379-64-1 n-hexyldichloroborane 
• 6926-45-0 1-azidohexane 
• 1222374-96-0 C₆H₃N₃O₇*C₁₂H₂₇N*C₈₅H₁₂₀O₁₅ 
• 549518-66-3 N,N-dihexyl-4-methylbenzenesulfonamide 
• 143-16-8 dihexylamine 
• 111-26-2 hexan-1-amine 
• 66-25-1 hexanal 
• 34695-21-1 N-hexylidenehexan-1-amine 
• 628-73-9 hexanenitrile 

Downstream Products

• 6949-28-6 N,N-dihexylnitrous amide 
• 1448244-34-5 C₁₂H₂₇N*C₃₂H₁₂BF₂₄^(1-)*H⁽¹⁺⁾ 

Relevant articles and documents

Osmium-Promoted Transformation of Alkyl Nitriles to Secondary Aliphatic Amines: Scope and Mechanism

The transformation of alkyl nitriles to symmetrical and asymmetrical secondary aliphatic amines promoted by the hexahydride complex OsH6(PiPr3)2 (1) is described, and the mechanisms of the reactions involved are established. Complex 1 catalyzes the aforementioned transformations of aryl-, pyridyl-, and alkoxy-functionalized alkyl nitriles with linear or branched chains. The formation of the secondary amines involves primary imines, primary amines, and secondary imines as organic intermediates. The reactions take place under mild conditions (toluene, 100 °C, and 4 bar of H2). Stoichiometric reactions of 1 with pivalonitrile and 2-methoxyacetonitrile have allowed us to isolate the trihydride azavinylidene derivatives OsH3{═N═CHR}(PiPr3)2 (R = tBu (3), CH2OMe (4)). Their formation involves the insertion of the N-C triple bond of the substrates into an Os-H bond of the unsaturated tetrahydride OsH4(PiPr3)2 (A), which is generated by reductive elimination of H2 from the hexahydride precursor. The reaction of these trihydride azavinylidene species with H2 is the key step for the reduction of the N-C triple bond of the nitriles. In the absence of H2, the attack of A to the azavinylidene ligand produces the rupture of its C(sp2)-C(sp3) bond. As a consequence of this attack and the presence of primary imines and amines in the reaction media, the binuclear complexes (PiPr3)2H4Os(μ-CN)OsH3{κ1-N-(NH═CHCH2OMe)}(PiPr3)2 (5) and (PiPr3)2H4Os(μ-CN)OsH3{κ1-N-(NH2CH2CH2OMe)}(PiPr3)2 (6) have been isolated and characterized by X-ray diffraction analysis, for 2-methoxyacetonitrile. DFT calculations reveal noticeable similarities between the hydrogenations of nitriles to primary imines and those of primary imines to primary amines.

Selective complexation of di-: N -hexylammonium salts by tailed porphyrin host

Novel types of tailed porphyrins have been synthesized and characterized. The tail was coordinated intramolecularly to zinc porphyrin, leading to the formation of a cavity. In the cavity, tailed porphyrins formed a complex with di-n-hexylammonium salts. T

Threading the calix[5]arene annulus

Slowly does it! Di-n-alkylammonium ions (such as 2 H+) thread the annulus of calix[5]arene 1 to yield stable [2] pseudorotaxanes. The ease of formation of this hitherto unknown family of interpenetrated supermolecules is predominantly determine