230285-11-7

Basic information

• Product Name: 5-(tert-butyldiphenylsiloxy)-1-phenyl-1-pentanone
• Synonyms: 5-(tert-butyldiphenylsiloxy)-1-phenyl-1-pentanone
• CAS NO: 230285-11-7
• Molecular Weight: 416.635
• Mol File: 230285-11-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 5-(tert-butyldiphenylsiloxy)-1-phenyl-1-pentanone(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(tert-butyldiphenylsiloxy)-1-phenyl-1-pentanone(230285-11-7)
• EPA Substance Registry System: 5-(tert-butyldiphenylsiloxy)-1-phenyl-1-pentanone(230285-11-7)

Safety Data

• Hazardous Substances Data: 230285-11-7(Hazardous Substances Data)

Upstream product

• 230285-12-8 5-(tert-butyldiphenylsiloxy)-1-phenyl-1-pentanol 
• 1011-62-7 5-hydroxy-1-phenylpentan-1-one 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 230285-21-9 1-acetoxy-5-(tert-butyldiphenylsiloxy)-1-methyl-1-phenylpentane 
• 15212-27-8 2-benzyltetrahydrofuran 
• 141883-58-1 1-acetoxy-1-methyl-1-phenyl-5-pentanol 
• 230285-14-0 1-phenyl-1-(2-tetrahydropyranyloxy)-5-pentanol 
• 230285-16-2 1-phenyl-5-(N-phthalimidoxy)-1-pentanol 
• 230285-17-3 1-(acetoxy)-1-phenyl-5-(N-phthalimidoxy)pentane 
• 230285-22-0 1-(acetoxy)-1-methyl-1-phenyl-5-(N-phthalimidoxy)pentane 
• 230285-15-1 1-phenyl-5-(N-phthalimidoxy)-1-(2-tetrahydropyranyloxy)pentane 
• 230285-18-4 1-(diethylphosphatoxy)-1-phenyl-5-(N-phthalimidoxy)pentane 
• 230285-13-9 5-(tert-butyldiphenylsiloxy)-1-phenyl-1-(2-tetrahydropyranyloxy)pentane 
• 230285-19-5 1-(diphenylphosphatoxy)-1-phenyl-5-(N-phthalimidoxy)pentane 
• 141765-56-2 1-methyl-1-phenyl-1,5-pentanediol 
• 145475-10-1 5-phenyl-1,4-pentanediol 
• 1011-61-6 1-phenylpentane-1,5-diol 

Relevant articles and documents

Microwave thermolysis - Part IX: A selective and rapid oxidation of benzylic alcohols using clay supported ammonium nitrate

The oxidation of a variety of benzylic alcohols to carbonyl compounds using clay-supported ammonium nitrate "clayan" under microwave irradiation is described. The selectivity and non-solvent condition are the important features of the procedure.

Synthesis of tetrahydrofurans by a tandem hydrogen atom abstraction/ radical nucleophilic displacement sequence

(equation presented) The reaction of a series of 5-(N-phthalimidoxy)-1-phenyl-1-(diphenylphosphatoxy)pentanes with triphenyltin hydride and AIBN provides alkoxy radicals which undergo 1,5-hydrogen atom abstraction to give β-(phosphatoxy)alkyl radicals. These radicals then take part in a radical nucleophilic displacement leading, after chain transfer, to tetrahydrofurans.