230310-74-4

Basic information

• Product Name: Et₂Ga(NH[C₆H₂(2,4,6-t-Bu)3])
• Synonyms: Et₂Ga(NH[C₆H₂(2,4,6-t-Bu)3])
• CAS NO: 230310-74-4
• Molecular Weight: 388.289
• Mol File: 230310-74-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Et₂Ga(NH[C₆H₂(2,4,6-t-Bu)3])(CAS DataBase Reference)
• NIST Chemistry Reference: Et₂Ga(NH[C₆H₂(2,4,6-t-Bu)3])(230310-74-4)
• EPA Substance Registry System: Et₂Ga(NH[C₆H₂(2,4,6-t-Bu)3])(230310-74-4)

Safety Data

• Hazardous Substances Data: 230310-74-4(Hazardous Substances Data)

Upstream product

• 230310-76-6 EtGa(NH[C₆H₂(2,4,6-t-Bu)3])2 
• 1115-99-7 triethyl gallium 
• 30914-08-0 diethylgallium chloride 
• 102745-24-4 2,4,6-tri-t-butylanilidolithium 

Downstream Products

• 1115-99-7 triethyl gallium 

Relevant articles and documents

Monomeric organogallium-nitrogen compounds. Chemistry of Et2GaNH[C6H2(2,4,6-t-Bu)3] with decomposition to the metallacycle {EtGaNH[C6H2(4,6-t-Bu)2CMe2CH 2-2]}2 and of EtGa{NH[C6H2(2,4,6-t-Bu)3]}2

Two monomeric gallium-nitrogen compounds, Et2GaNH[C6H2(2,4,6-t-Bu)3] and EtGa{NH-[C6H2(2,4,6-t-Bu)3]}2, have been prepared by metathetical reactions between either Et2GaCl or EtGaCl2, as appropriate, and LiNH[C6H2(2,4,6-t-Bu)3] and have been characterized fully. Cryoscopic molecular weight studies demonstrated both compounds to be monomeric in benzene solution, whereas an X-ray structural study of the latter identified a monomer. The compound Et2GaNH[C6H2(2,4,6-t-Bu)3] decomposes at room temperature to form a new metallacyclic derivative {EtGaNH[C6H2(4,6-t-Bu)2(CMe2CH 2-2)]}2 GaEt3, and H2N[C6H2-(2,4,6-t-Bu)3]. A 1H NMR spectral study and an X-ray structural study were used to elucidate its structure. The compound EtGa{NH[C6H2(2,4,6-t-Bu)3]}2 does not decompose to the metallacycle, but it reacts readily with GaEt3 to form Et2GaNH[C6H2(2,4,6-t-Bu)3].