23074-42-2Relevant articles and documents
Reactions of 1,3-dehydroadamantane with inorganic oxygen-free acids
Butov,Mokhov,Burmistrov,Saad,Pitushkin
, p. 1276 - 1278 (2014)
A convenient and efficient procedure has been developed for the synthesis of 1-azidoadamantane, 1-adamantyl isocyanate, and 1-adamantyl isothiocyanate by reaction of 1,3-dehydroadamantane with hydrazoic, isocyanic, and isothiocyanic acids, respectively, under mild conditions. The reaction of 1,3-dehydroadamantane with hydrogen cyanide under analogous conditions gives adamantane-1-carbonitrile in a poor yield which may be improved using hexane as solvent.
Lewis Acid-Catalyzed Preparation of Bridge-head Adamantanoid Nitriles from their Corresponding Halides and Trimethylsilyl Cyanide
Olah, George A.,Farooq, Omar,Surya Prakash, G. K.
, p. 1140 - 1142 (1985)
Bridge-head adamantyl and diamantyl nitriles 2 have been prepared in good yields by refluxing the corresponding halides 1 with trimethylsilyl cyanide and tin(IV) chloride in dichloromethane.
Direct C(sp3)-H Cyanation Enabled by a Highly Active Decatungstate Photocatalyst
Kim, Kunsoon,Lee, Seulchan,Hong, Soon Hyeok
supporting information, p. 5501 - 5505 (2021/07/26)
A highly efficient, direct C(sp3)-H cyanation was developed under mild photocatalytic conditions. The method enabled the direct cyanation of various C(sp3)-H substrates with excellent functional group tolerance. Notably, complex natural products and bioactive compounds were efficiently cyanated.
Oxidation of aldehydes to nitriles with an oxoammonium salt: Preparation of piperonylonitrile
Kaetzel, Nathaniel D.,Kelly, Christopher B.,Lambert, Kyle M.
, p. 294 - 313 (2020/11/09)
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