23589-13-1

Basic information

• Product Name: N-(3-Methyl-2-butenyl)-7-β-D-ribofuranosyl-7H-pyrrolo[2,3-d]pyrimidin-4-amine
• Synonyms: N-(3-Methyl-2-butenyl)-7-β-D-ribofuranosyl-7H-pyrrolo[2,3-d]pyrimidin-4-amine
• CAS NO: 23589-13-1
• Molecular Formula: C16H22N4O4
• Molecular Weight: 334.37028
• Mol File: 23589-13-1.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N-(3-Methyl-2-butenyl)-7-β-D-ribofuranosyl-7H-pyrrolo[2,3-d]pyrimidin-4-amine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(3-Methyl-2-butenyl)-7-β-D-ribofuranosyl-7H-pyrrolo[2,3-d]pyrimidin-4-amine(23589-13-1)
• EPA Substance Registry System: N-(3-Methyl-2-butenyl)-7-β-D-ribofuranosyl-7H-pyrrolo[2,3-d]pyrimidin-4-amine(23589-13-1)

Safety Data

• Hazardous Substances Data: 23589-13-1(Hazardous Substances Data)

Upstream product

• 69-33-0 tubercidin 
• 870-63-3 prenyl bromide 
• 85572-96-9 4-(3-Methyl-2-butenylamino)-2-(methylthio)-7-(β-D-ribofuranosyl)-7H-pyrrolo<2,3-d>pyrimidin 
• 85572-94-7 4-chloro-2-(methylthio)-7-(β-D-ribofuranosyl)-7H-pyrrolo<2,3-d>pyrimidine 
• 94773-30-5 4-Amino-2-(methylthio)-7-(β-D-ribofuranosyl)-7H-pyrrolo<2,3-d>pyrimidin 

Relevant articles and documents

Anomers of Tubercidin Derivatives with 2-Methylthio and N4-(Δ2-Isopentenyl) Residues

Starting with the chloronucleosides 3a and 4a the anomers 1 and 2 of 2-(methylthio)tubercidin were prepared.They are desulfurized to tubercidin (3c) and its α-anomer 4c.Desulfurization of the N4-(Δ2-isopentenyl) compounds 3b and 4b yields 3d and 4d; due to hydrogenation the by-products 3e and 4e are formed.Isopentylation of tubercidin followed by Dimroth rearrangement also gives N4-(Δ2-isopentenyl)tubercidin (3d).From the 1J(C,H) coupling constants of the glyconic moiety the sequence of the 13C signals of the α-anomer 2 was deduced.The 3J(C-6,1'-H) couplings of tubercidins gave the torsion angle χ which is found to be in the anti region.