236401-66-4

Basic information

• Product Name: (3E,5E,7S,8S,11E,13E,15S,16S)-8,16-bis[(1S,2S,3S,4R)-2-hydroxy-4-(4-methoxybenzyloxy)-1,3-dimethylpentyl]-7,15-dimethyl-1,9-dioxacyclohexadeca-3,5,11,13-tetraene-2,10-dione
• Synonyms: (3E,5E,7S,8S,11E,13E,15S,16S)-8,16-bis[(1S,2S,3S,4R)-2-hydroxy-4-(4-methoxybenzyloxy)-1,3-dimethylpentyl]-7,15-dimethyl-1,9-dioxacyclohexadeca-3,5,11,13-tetraene-2,10-dione
• CAS NO: 236401-66-4
• Molecular Weight: 777.008
• Mol File: 236401-66-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3E,5E,7S,8S,11E,13E,15S,16S)-8,16-bis[(1S,2S,3S,4R)-2-hydroxy-4-(4-methoxybenzyloxy)-1,3-dimethylpentyl]-7,15-dimethyl-1,9-dioxacyclohexadeca-3,5,11,13-tetraene-2,10-dione(CAS DataBase Reference)
• NIST Chemistry Reference: (3E,5E,7S,8S,11E,13E,15S,16S)-8,16-bis[(1S,2S,3S,4R)-2-hydroxy-4-(4-methoxybenzyloxy)-1,3-dimethylpentyl]-7,15-dimethyl-1,9-dioxacyclohexadeca-3,5,11,13-tetraene-2,10-dione(236401-66-4)
• EPA Substance Registry System: (3E,5E,7S,8S,11E,13E,15S,16S)-8,16-bis[(1S,2S,3S,4R)-2-hydroxy-4-(4-methoxybenzyloxy)-1,3-dimethylpentyl]-7,15-dimethyl-1,9-dioxacyclohexadeca-3,5,11,13-tetraene-2,10-dione(236401-66-4)

Safety Data

• Hazardous Substances Data: 236401-66-4(Hazardous Substances Data)

Upstream product

• 236401-80-2 (1E,3S,4S,5R,6S,7S,8R)-1-iodo-8-(4-methoxybenzyloxy)-3,5,7-trimethylnon-1-en-4,6-diol 
• 6372-02-7 (E)-3-iodoacrylic acid 

Downstream Products

• 236401-81-3 (3E,5E,7S,8S,11E,13E,15S,16S)-8,16-bis[(1R,2S,3R,4R)-4-(4-methoxybenzyloxy)-2-triethylsilyloxy-1,3-dimethylpentyl]-7,15-dimethyl-1,9-dioxacyclohexadeca-3,5,11,13-tetraene-2,10-dione 

Relevant articles and documents

Total synthesis of elaiolide using a copper(l)-promoted stille cyclodimerization reaction

(equation presented) Elaiolide (2) The 16-membered macrodiolide elaiolide (2) has been prepared in 20 steps from the ketone (S)-8 in 9.3% overall yield with a diastereoselectivity of 76%. Key steps included the copper(l) thiophene-2-carboxylate promoted c