23661-58-7Relevant articles and documents
The Reaction of Bromo- and Iodo-phosphoranes with Unactivated Coarse Grain Manganese Metal Powder to Yield and n> (X = Br or I) by Insertion of Mn into the P-X Bond. The Crystal Structure of
Godfrey, Stephen M.,McAuliffe, Charles A.,Pritchard, Robin G.
, p. 371 - 376 (2007/10/02)
The novel reaction of crude manganese metal powder with dibromo- and diiodo-phosphoranes, R3PX2, has been studied.Reaction of the phosphoranes R3PI2 (R = phenyl or substituted aryl) with manganese allows insertion of the metal into P-X bonds and gives the
