23731-39-7

Basic information

• Product Name: METHYL-D3 FORMATE
• Synonyms: METHYL-D3 FORMATE
• CAS NO: 23731-39-7
• Molecular Formula: C₂H₄O₂
• Molecular Weight: 63.07
• Mol File: 23731-39-7.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• Storage Temp.: 0-6°C
• CAS DataBase Reference: METHYL-D3 FORMATE(CAS DataBase Reference)
• NIST Chemistry Reference: METHYL-D3 FORMATE(23731-39-7)
• EPA Substance Registry System: METHYL-D3 FORMATE(23731-39-7)

Safety Data

• Hazardous Substances Data: 23731-39-7(Hazardous Substances Data)

Usage

Uses

Methyl-d3 Formate (CAS# 23731-39-7) is a useful isotopically labeled research compound.

Upstream product

• 108864-10-4 C⁽²⁾H₅O⁽¹⁺⁾ 
• 111515-57-2 bis(dimethoxymethyl) peroxide 
• 811-98-3 d⁽⁴⁾-methanol 
• 185252-83-9 8-Benzyl-2-tert-butyl-5-hydroperoxy-6-(4-methoxy-phenyl)-5H-imidazo[1,2-a]pyrazin-3-one 
• 1849-29-2 1,1,1-trideuteromethanol 
• 124-38-9 carbon dioxide 

Downstream Products

• 1825-63-4 trimethyl(propoxy)silane 
• 19108-51-1 trimethyl-trideuteriomethoxy-silane 
• 75-21-8 oxirane 
• 125518-33-4 C₃H₉O₂Si^(1-) 

Relevant articles and documents

Cascade catalysis for the homogeneous hydrogenation of CO2 to methanol

This communication demonstrates the homogeneous hydrogenation of CO 2 to CH3OH via cascade catalysis. Three different homogeneous catalysts, (PMe3)4Ru(Cl)(OAc), Sc(OTf) 3, and (PNN)Ru(CO)(H), operate in sequence to promote this transformation.

Bis(dimethoxymethyl) peroxide and bis(1,1-dimethoxyethyl) peroxide

The title compounds 1 and 2, the first examples of peroxides polysubstituted at the α and α' positions by alkoxy groups, are formed by benzophenone sensitized photooxygenation of trimethoxymethane and 1,1,1-trimethoxyethane, respectively.No peroxide was formed from tetramethoxymethane.Allowing 98percent hydrogen peroxide and trimethylmethane to stand results in an 80percent yield of 1, so that 1 and 2 are probably formed by such a disproportionation reaction during photooxygenation.Compound 1 is converted quantitatively to methanol, methyl formate, and dimethyl carbonate in pyridine solution at 60 deg C.In acidic methanol both 1 and 2 undergo solvolysis rapidly with exclusive cleavage of the carbon - peroxy oxygen bond.Signals for the ether and peroxy oxygens of 1 appear at 34 and 263 ppm and those of 2 appear at 40 and 264 ppm in the 17O nuclear magnetic resonance spectrum.Luminescence results when 1 and 2 are heated to 150 deg C.