23822-17-5

Basic information

• Product Name: tris(2,4,6-trimethylphenyl)antimony
• Synonyms: tris(2,4,6-trimethylphenyl)antimony
• CAS NO: 23822-17-5
• Molecular Weight: 479.309
• Mol File: 23822-17-5.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: tris(2,4,6-trimethylphenyl)antimony(CAS DataBase Reference)
• NIST Chemistry Reference: tris(2,4,6-trimethylphenyl)antimony(23822-17-5)
• EPA Substance Registry System: tris(2,4,6-trimethylphenyl)antimony(23822-17-5)

Safety Data

• Hazardous Substances Data: 23822-17-5(Hazardous Substances Data)

Upstream product

• 10025-91-9 antimony(III) chloride 
• 5806-59-7 mesityllithium 
• 576-83-0 2,4,6-trimethylphenyl bromide 
• 2633-66-1 2-mesitylmagnesium bromide 

Downstream Products

• 10025-91-9 antimony(III) chloride 
• 121810-02-4 dimesitylstibane 
• 113002-54-3 tris(2,4,6-trimethylphenyl)antimonydihydroxide 
• 113002-55-4 tris(2,4,6-trimethylphenyl)antimony(V)oxide 
• 23902-44-5 ({(CH₃)3C₆H₂}3SbCH₃)⁽¹⁺⁾*{BF₄}^(1-)=({(CH₃)3C₆H₂}3SbCH₃){BF₄} 
• 106870-56-8 mesitylantimony dichloride 
• 106870-55-7 chlorodimesitylstibane 
• 83609-14-7 difluorotrimesitylantimony 
• 382149-03-3 [(trichloroacetyl)imino]tris(2,4,6-trimethylphenyl)-λ5-stibane (15)N-labeled 
• 382148-92-7 [(trichloroacetyl)imino]tris(2,4,6-trimethylphenyl)-λ5-stibane 
• 1229029-60-0 [Au(trimesitylstibine)2]SO₃CF₃ 
• 1229029-55-3 AuCl(trimesitylstibine) 
• 1229029-59-7 [Au(trimesitylstibine)2]ClO₄ 
• 214360-78-8 2,4,6-trimethylbenzeneboronic acid neopentyl glycol cyclic ester 

Relevant articles and documents

Unsupported monomeric stibine oxides (R3SbO) remain undiscovered

Attempts to investigate the properties and reactivity of the stiboryl moiety (R3Sb+-O?or R3SbO), as in monomeric stibine oxides free of interaction with Lewis acids/bases, led us to conclude that this functional

Fourier-transform Raman and infrared spectra and normal coordinate analysis of the triphenyl compounds and their methyl-, methoxy- and fluoro-substituted derivatives of arsenic, antimony and bismuth

The Fourier transform (FT)-Raman and infrared (IR) spectra of triphenyl-, perdeuterated triphenyl-, tris(2-methylphenyl)-, tris(3-methylphenyl)-, tris(2,4,6-trimethylphenyl)-, tris(2-methoxyphenyl)-, tris(3-methoxyphenyl)-, tris(3-fluorophenyl)- and tris(

Tri- and di-arylantimony( V) thiocyanates and mixed halide thiocyanates; crystal structure of triphenylantimony( V) di-isothiocyanate

A series of triarylantimony(V) dithiocyanates has been prepared by oxidising the appropriate antimony(III) compound with thiocyanogen. IR and 14N NMR spectroscopy indicate the presence of terminally N-bonded thiocyanate groups and this has been confirmed by a crystal structure determination for the SbPh3(NCS)2. The asymmetric unit contains three independent trigonal bipyramidal molecules, which differ in the orientations of the axial N-bonded thiocyanates and the phenyl groups in the equatorial plane, and there may be weak C-H ... S interactions. Treatment of SbPh2X3, where X = Br or Cl, with KSCN gave K[SbPh2(NCS)4] and attempts to prepare SbPh2(NCS)3 and related diphenylantimony(V) mixed halide thiocyanates, SbPh2Xn(NCS)3 - n where X = Br or Cl and n = 0-2, by treating appropriate diphenylantimony(III) precursors with thiocyanogen or thiocyanogen bromide or chloride gave products which in many cases underwent reorganisation during recrystallisation. Samples of SbPh2(NCS)3, SbPh2Br(NCS)2, SbPh2Br2(NCS) and SbPh2Cl2(NCS), and SbPh3Br(NCS) have, however, been isolated as microcrystalline solids.