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2386-87-0

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  • 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate 2386-87-0 /manufacturer/low price/high quality/in stock

    Cas No: 2386-87-0

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  • High Quality 99% 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate 2386-87-0 ISO Manufacturer

    Cas No: 2386-87-0

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2386-87-0 Usage

Description

3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate (EEC) is a cycloaliphatic epoxy monomer synthesized by the reaction of 3′-cyclohexenylmethyl 3-cyclohexenecarboxylate with peracetic acid. It is a pale yellow to colorless transparent liquid with an aliphatic backbone and molecular structure that provides useful properties such as thermal stability, weatherability, and electrical conductivity.

Uses

Used in Aerospace Industry:
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate is used as a resin for [application reason] in the aerospace industry. Its thermal stability, weatherability, and electrical conductivity make it a suitable choice for this application.
Used in Electronics Industry:
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate is used as an adhesive and a composite material for [application reason] in the electronics industry. Its properties of thermal stability and electrical conductivity contribute to its effectiveness in this field.
Used in Automobile Industry:
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate is used as a resin in the automobile industry for [application reason]. Its combination of thermal stability, weatherability, and electrical conductivity makes it an ideal material for various automotive applications.
Used as a Reactive Diluent:
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate is used as a reactive diluent for [application reason]. Its properties allow it to be an effective component in the formulation of various products.
Used for Filament Winding:
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate is used in filament winding as a [application type] for [application reason]. Its characteristics make it suitable for this specific application.
Used as an Acid Scavenger:
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate is used as an acid scavenger for [application reason]. Its ability to neutralize acids makes it a valuable component in certain industrial processes.
Used as a Plasticizer:
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate is used as a plasticizer for [application reason]. Its properties enhance the flexibility and workability of certain materials.
Safety Note:
Vapor hazard is slight at ambient temperature due to its moderately high boiling point. However, skin contact should be avoided to ensure safety during handling and use.

Flammability and Explosibility

Nonflammable

Check Digit Verification of cas no

The CAS Registry Mumber 2386-87-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,3,8 and 6 respectively; the second part has 2 digits, 8 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 2386-87:
(6*2)+(5*3)+(4*8)+(3*6)+(2*8)+(1*7)=100
100 % 10 = 0
So 2386-87-0 is a valid CAS Registry Number.
InChI:InChI=1/C14H20O4/c15-14(9-2-4-11-13(6-9)18-11)16-7-8-1-3-10-12(5-8)17-10/h8-13H,1-7H2

2386-87-0 Well-known Company Product Price

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  • Aldrich

  • (407208)  3,4-Epoxycyclohexylmethyl3,4-epoxycyclohexanecarboxylate  

  • 2386-87-0

  • 407208-50ML

  • 579.15CNY

  • Detail
  • Aldrich

  • (407208)  3,4-Epoxycyclohexylmethyl3,4-epoxycyclohexanecarboxylate  

  • 2386-87-0

  • 407208-250ML

  • 1,993.68CNY

  • Detail

2386-87-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate

1.2 Other means of identification

Product number -
Other names ERL-4211

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Paint additives and coating additives not described by other categories
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:2386-87-0 SDS

2386-87-0Synthetic route

3-cyclohexene-1-carboxylic acid 3-cyclohexen-1-ylmethyl ester
2611-00-9

3-cyclohexene-1-carboxylic acid 3-cyclohexen-1-ylmethyl ester

3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
2386-87-0

3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate

Conditions
ConditionsYield
With phosphotungstic acid; trioctylmethylammonium acetate; phosphoric acid; dihydrogen peroxide; sodium carbonate In water; toluene at 50℃; for 15h; Inert atmosphere;94%
With 1H-imidazole; tristetrahexylammonium tetrakis(diperoxotungsto) phosphate; dihydrogen peroxide In water; acetonitrile at 49.84℃; under 760.051 Torr; for 24h; Reagent/catalyst; Inert atmosphere;82%
With dihydrogen peroxide; acetonitrile; triethylamine In water at 60℃; for 10h; Conversion of starting material;46%
3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
2386-87-0

3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate

carbon dioxide
124-38-9

carbon dioxide

C16H20O8

C16H20O8

Conditions
ConditionsYield
With tetrabutylammomium bromide In neat (no solvent) at 100℃; for 12h; chemoselective reaction;99%
3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
2386-87-0

3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate

carbon dioxide
124-38-9

carbon dioxide

C16H20O8

C16H20O8

Conditions
ConditionsYield
With calcium iodide In neat (no solvent) at 90℃; under 37503.8 Torr; for 48h; diastereoselective reaction;98%
3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
2386-87-0

3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate

methacryloyl anhydride
760-93-0

methacryloyl anhydride

3,4-bis(methacryloyloxy)cyclohexanecarboxylic acid 3,4-bis(methacryloyloxy)cyclohexylmethyl ester

3,4-bis(methacryloyloxy)cyclohexanecarboxylic acid 3,4-bis(methacryloyloxy)cyclohexylmethyl ester

Conditions
ConditionsYield
With benzyltrimethylammonium chloride; 4-methoxy-phenol at 100℃; for 24h;81%
4-butanolide
96-48-0

4-butanolide

3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
2386-87-0

3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate

Reaxys ID: 11465227

Reaxys ID: 11465227

Conditions
ConditionsYield
at 97 - 100℃; for 3h;
3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
2386-87-0

3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate

poly(bisphenol A-co-epichlorohydrin) glycidyl end-capped

poly(bisphenol A-co-epichlorohydrin) glycidyl end-capped

[poly(bisphenol A-co-epichlorohydrin) glycidyl end-capped]-(3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate) copolymer

[poly(bisphenol A-co-epichlorohydrin) glycidyl end-capped]-(3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate) copolymer

Conditions
ConditionsYield
With CD-1012 near-IR femtosecond irradiation;
3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
2386-87-0

3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate

Epon SU-8

Epon SU-8

(Epon SU-8)-(3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate) copolymer

(Epon SU-8)-(3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate) copolymer

Conditions
ConditionsYield
With CD-1010 near-IR femtosecond irradiation;
3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
2386-87-0

3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate

poly[7-oxa-bicyclo[4.1.0]heptane-3-carboxylic acid 7-oxa-bicyclo[4.1.0]hept-3-ylmethyl ester], photopolymerization; monomer: UVR 6110

poly[7-oxa-bicyclo[4.1.0]heptane-3-carboxylic acid 7-oxa-bicyclo[4.1.0]hept-3-ylmethyl ester], photopolymerization; monomer: UVR 6110

Conditions
ConditionsYield
With (4-iPr-phenyl)-4'-methylphenyliodonium (C6F5)4-gallate Kinetics; Further Variations:; Reagents; UV-irradiation;
1,2-propylene cyclic carbonate
108-32-7

1,2-propylene cyclic carbonate

3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
2386-87-0

3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate

Reaxys ID: 11465275

Reaxys ID: 11465275

Conditions
ConditionsYield
Cr3+ catalyst at 75 - 94℃; for 3h;

2386-87-0Downstream Products

2386-87-0Relevant articles and documents

Safe, environment-friendly and controllable synthetic process of di-epoxide

-

Paragraph 0084-0100; 0298-0312, (2019/10/01)

The invention relates to the field of synthesis of epoxide, and more specifically, relates to a safe, environment-friendly and controllable synthetic process of di-epoxide. The synthetic process of the di-epoxide at least comprises the following steps: mixing diolefin, carboxylic acids, basic salt and solvent, and cooling; dropwise adding a hydrogen peroxide solution for 1-12 h; standing for layering to obtain a lower layer organic phase-1, washing the organic phase-1 with a cleaning solution, and standing for layering to obtain a lower layer organic phase-2; purifying. The reaction system ofthe synthetic process is simple, environmentally friendly, safe and controllable, is low in production cost, and can meet the requirements of technical economy; the prepared di-epoxide is high in purity and yield and low in solvent content, chroma and halogen content, and is suitable for large-scale industrial production.

The method for producing the epoxy compound

-

Paragraph 0063, (2017/05/26)

PROBLEM TO BE SOLVED: To provide a high-purity epoxy compound.SOLUTION: (1) A method for producing the epoxy compound includes subjecting a compound having a carbon-carbon double bond to an oxidation reaction in the presence of hydrogen peroxide, a quaternary ammonium salt, and polyacids and subsequently removing the quaternary ammonium salt remaining in the reaction mixture by a phenol formaldehyde-based resin. (2) The production method described in (1) uses the phenol formaldehyde-based resin having a phenolic hydroxyl group and an amino group as functional groups.

Highly selective epoxidation of cycloaliphatic alkenes with aqueous hydrogen peroxide catalyzed by [PO4{WO(O2) 2}4]3-/imidazole

Kamata, Keigo,Sugahara, Kosei,Ishimoto, Ryo,Nojima, Susumu,Okazaki, Motoya,Matsumoto, Takaya,Mizuno, Noritaka

, p. 2327 - 2332 (2014/08/18)

In the presence of imidazole as an additive, a phosphorus-containing tetranuclear peroxotungstate, THA3[PO4{WO(O 2)2}4] (I, THA=tetra-n-hexylammonium), could act as an efficient catalyst for epoxidation of cycloaliphatic alkenes with 30% aqueous hydrogen peroxide (H2O2). Compound I showed higher catalytic activity and selectivity to epoxide than other tungstates. By using the I/imidazole system, various kinds of cycloaliphatic alkenes could be highly selectively converted into the acid-sensitive epoxides including industrially important diepoxides in high to excellent yields under the almost stoichiometric conditions. The 1H NMR spectroscopy showed that imidazole would work not only as a proton acceptor but also as a Lewis base to remarkably suppress the acid-catalyzed ring opening of epoxides.

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