238742-40-0

Basic information

• Product Name: (C₆H₅)2PNHC₆H₄P(C₆H₅)2
• Synonyms: (C₆H₅)2PNHC₆H₄P(C₆H₅)2
• CAS NO: 238742-40-0
• Molecular Weight: 461.483
• Mol File: 238742-40-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (C₆H₅)2PNHC₆H₄P(C₆H₅)2(CAS DataBase Reference)
• NIST Chemistry Reference: (C₆H₅)2PNHC₆H₄P(C₆H₅)2(238742-40-0)
• EPA Substance Registry System: (C₆H₅)2PNHC₆H₄P(C₆H₅)2(238742-40-0)

Safety Data

• Hazardous Substances Data: 238742-40-0(Hazardous Substances Data)

Upstream product

• 1079-66-9 chloro-diphenylphosphine 
• 65423-44-1 (2-diphenylphosphino)benzeneamine 

Downstream Products

• 370567-84-3 (C₆H₅)2P(S)NHC₆H₄P(C₆H₅)2S 
• 238742-52-4 RuCl2(η(3):η(3).-C10H16)(Ph2PNHC6H4PPh2-P(N)) 
• 238742-49-9 RuCl2(η(6)-C6Me6)(Ph2PNHC6H4PPh2-P(N)) 
• 370567-80-9 [NiCl₂((C₆H₅)2PNHC₆H₄P(C₆H₅)2)] 
• 370567-77-4 [Pt(CH₃)2((C₆H₅)2PNHC₆H₄P(C₆H₅)2)] 
• 370567-76-3 [PtI₂((C₆H₅)2PNHC₆H₄P(C₆H₅)2)] 
• 370567-75-2 [PtBr₂((C₆H₅)2PNHC₆H₄P(C₆H₅)2)] 
• 238742-43-3 RhCl2(η(5)-C5Me5)(Ph2PNHC6H4PPh2-P(N)) 
• 238742-45-5 IrCl2(η(5)-C5Me5)(Ph2PNHC6H4PPh2-P(N)) 
• 370567-74-1 [PtCl₂((C₆H₅)2PNHC₆H₄P(C₆H₅)2)] 

Relevant articles and documents

Synthesis and characterization of lithium complexes of 2- (diphenylphosphanylamino)pyridine and N,2-bis(diphenylphosphanyl)benzeneamine

Lithium complexes of 2-(diphenylphosphinoamino)pyridine and N,2-bis(diphenylphosphanyl)benzeneamine have been synthesized from the corresponding neutral compounds. In the former complex, the metal ion is coordinated to both nitrogen atoms, forming a constrained four-membered ring, whereas the latter complex forms a five-membered ring as the metal ion coordinates preferentially to the phosphorus atom. Coordination of the metal ion in both complexes is dictated primarily by soft-hard interactions and, subsequently, by the constrained geometry of the ring formed. Both lithium complexes and the corresponding neutral compounds have been characterized by single-crystal X-ray diffraction. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.