238747-46-1

Basic information

• Product Name: Cyclopentanamine, 2-(phenylthio)-, (1R,2R)-rel- (9CI)
• Synonyms: Cyclopentanamine, 2-(phenylthio)-, (1R,2R)-rel- (9CI)
• CAS NO: 238747-46-1
• Molecular Formula: C11H15NS
• Molecular Weight: 193.3085
• Product Categories: CYCLOPENTANE
• Mol File: 238747-46-1.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Cyclopentanamine, 2-(phenylthio)-, (1R,2R)-rel- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopentanamine, 2-(phenylthio)-, (1R,2R)-rel- (9CI)(238747-46-1)
• EPA Substance Registry System: Cyclopentanamine, 2-(phenylthio)-, (1R,2R)-rel- (9CI)(238747-46-1)

Safety Data

• Hazardous Substances Data: 238747-46-1(Hazardous Substances Data)

Upstream product

• 285-63-2 6-azabicyclo<3.1.0>hexane 
• 108-98-5 thiophenol 

Relevant articles and documents

Ring-opening of NH-aziridines with thiols in ionic liquids: Application to the synthesis of aminosulfide catalysts for asymmetric epoxidation of aldehydes

The ring opening of NH-aziridines with thiols was found to proceed in good yield at room temperature in the presence of an ionic liquid1-butyl-3- methylimidazolium chloride (BMIM chloride). This mild methodology was applied to the synthesis of a camphor-derived chiral aminosulfide. The sulfide was used to generate a sulfur ylide, which effected an asymmetric epoxidation of benzaldehyde (e.r. 85:15, trans:cis 90:10, 87% yield). The amino group enabled easy recovery of the sulfide (98% yield) after the reaction by a simple acid/base extraction. Copyright Taylor & Francis Group.