239089-29-3

Basic information

• Product Name: (1'R)-5-(1'-Hydroxybut-3'-enyl)-5-p-methoxybenzyloxymethyl-2,2-dimethyl-5-(1'-trimethylsilyloxybut-3'-enyl)-1,3-dioxane
• Synonyms: (1'R)-5-(1'-Hydroxybut-3'-enyl)-5-p-methoxybenzyloxymethyl-2,2-dimethyl-5-(1'-trimethylsilyloxybut-3'-enyl)-1,3-dioxane
• CAS NO: 239089-29-3
• Molecular Weight: 336.428
• Mol File: 239089-29-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1'R)-5-(1'-Hydroxybut-3'-enyl)-5-p-methoxybenzyloxymethyl-2,2-dimethyl-5-(1'-trimethylsilyloxybut-3'-enyl)-1,3-dioxane(CAS DataBase Reference)
• NIST Chemistry Reference: (1'R)-5-(1'-Hydroxybut-3'-enyl)-5-p-methoxybenzyloxymethyl-2,2-dimethyl-5-(1'-trimethylsilyloxybut-3'-enyl)-1,3-dioxane(239089-29-3)
• EPA Substance Registry System: (1'R)-5-(1'-Hydroxybut-3'-enyl)-5-p-methoxybenzyloxymethyl-2,2-dimethyl-5-(1'-trimethylsilyloxybut-3'-enyl)-1,3-dioxane(239089-29-3)

Safety Data

• Hazardous Substances Data: 239089-29-3(Hazardous Substances Data)

Upstream product

• 239089-25-9 5,5-Bis(p-methoxybenzyloxymethyl)-2,2-dimethyl-1,3-dioxane 
• 239089-26-0 (5-(((4-methoxybenzyl)oxy)methyl)-2,2-dimethyl-1,3-dioxan-5-yl)methanol 
• 239089-27-1 9-(4-methoxyphenyl)-3,3-dimethyl-2,4,8,10-tetraoxaspiro[5.5]undecane 
• 20605-01-0 diethyl bis(hydroxymethyl)malonate 
• 51335-75-2 2,2-Dimethyl-1,3-dioxacyclohexane-5,5-dicarboxylic acid,diethyl ester 
• 770-74-1 2,2-dimethyl-5,5-bis(hydroxymethyl)-1,3-dioxane 
• 239089-28-2 5-Formyl-5-p-methoxybenzyloxymethyl-2,2-dimethyl-1,3-dioxane 
• 1730-25-2 allylmagnesium bromide 

Downstream Products

• 239089-33-9 (1'R,3'S)-5-{1',3'-Bistriethylsilyloxy-3'-[furan-2''(5''H)-on-4''-yl]propyl}-5-p-methoxybenzyloxymethyl-2,2-dimethyl-1,3-dioxane 
• 239089-40-8 (1'R,3'R)-5-{1',3'-Dihydroxy-3'-[furan-2''(5''H)-on-4''-yl]propyl}-5-p-methoxybenzyloxymethyl-2,2-dimethyl-1,3-dioxane 
• 239089-32-8 (1'R,3'S)-5-{1',3'-Dihydroxy-3'-[furan-2''(5''H)-on-4''-yl]propyl}-5-p-methoxybenzyloxymethyl-2,2-dimethyl-1,3-dioxane 

Relevant articles and documents

Synthetic studies on azadirachtin: An efficient asymmetric synthesis of the highly functionalized tricyclic decalin part of azadirachtin

The detailed examination of intramolecular Diels-Alder reactions of several structurally related trienes led to construction of the desired tricyclic decalin moiety of azadirachtin with the α-hydroxyl groups at C1 and C3 as well as the oxygenated substituent at C8 in the naturally occurring form in good yields.