240483-08-3Relevant articles and documents
Synthesis of C-glycosides via radical cyclization reactions with a vinylsilyl tether. Control of the reaction course by a change in the conformation of the pyranose ring due to steric repulsion between adjacent bulky protecting groups
Yahiro, Yumi,Ichikawa, Satoshi,Shuto, Satoshi,Matsuda, Akira
, p. 5527 - 5531 (1999)
A stereoselective method for introducing a C2-unit at the 1α- and 1β- postions of D-glucose and D-mannose, respectively, via a radical cyclization reaction with vinylsilyl group as a temporary connecting tether, was developed. The radical cyclization of D