24075-47-6Relevant articles and documents
Quantitative determination of 9-methylcarbazoles in cigarette smoke.
Hoffmann,Rathkamp,Nesnow
, p. 1256 - 1259 (1969)
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Method for preparing carbazole compound
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Paragraph 0068; 0069; 0070; 0071; 0072; 0073, (2019/04/13)
The invention discloses a method for synthesizing a carbazole compound by utilizing N,N-di-substituted o-aminobenzoate compound. The synthesis method comprises the following steps of adopting a palladium salt as a catalyst, mixing the palladium salt, the N,N-di-substituted o-aminobenzoate compound, an oxidant and an organic solvent, and carrying out heating reaction to obtain the carbazole compound. The method disclosed by the invention has the advantages that the preparation route is short, the universality of a substrate is good, the synthesis yield is high, the used catalyst is simple and easy to obtain and the like.
Photoinduced Cross-Coupling of Amines with 1,2-Diiodobenzene and Its Application in the Synthesis of Carbazoles
Zhao, Xinxin,Chen, Ming,Huang, Binbin,Yang, Chao,Gao, Yuan,Xia, Wujiong
, p. 2981 - 2989 (2018/05/15)
A facile and efficient process for the preparation of various tertiary aminobenzenes and carbazole derivatives via photoinduced cross-coupling of amines with 1,2-diiodobenzene is reported. Mechanistic investigations indicate that the transformation proceeds via nucleo-philic addition of an amine to the benzyne intermediate accompanied with a proton transfer process, followed by an oxidative cyclization of the generated diphenylamine to furnish the corresponding carbazole products.