2408-08-4Relevant articles and documents
An efficient and practical approach to trifluoromethylthiolation of α-haloketones/α-haloarylmethanes
Jiang, Min,Zhu, Fangxia,Xiang, Haoyue,Xu, Xing,Deng, Lianfu,Yang, Chunhao
, p. 6935 - 6939 (2015/06/25)
An efficient and practical approach to trifluoromethylthiolation of α-haloketones/α-haloarylmethanes was developed. The transformation employs only AgSCF3 and KI in situ generated active nucleophilic trifluoromethylthio species and cleanly occurs in up to quantitative yield at room temperature, thereby providing an unprecedentedly easy entry to various α-SCF3-substituted ketones/arylmethanes.
Trifluoro methylthiomethyl benzene derivatives and process for production same
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, (2008/06/13)
The present invention lies in a process for producing a trifluoromethylthiomethylbenzene derivative represented by the following general formula (2): (wherein R is a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an alkoxycarbonyl group,