24118-25-0

Basic information

• Product Name: 3,6-diamino-2,5-dichloro-1,4-hydroquinone
• Synonyms: 3,6-diamino-2,5-dichloro-1,4-hydroquinone
• CAS NO: 24118-25-0
• Molecular Weight: 209.032
• Mol File: 24118-25-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3,6-diamino-2,5-dichloro-1,4-hydroquinone(CAS DataBase Reference)
• NIST Chemistry Reference: 3,6-diamino-2,5-dichloro-1,4-hydroquinone(24118-25-0)
• EPA Substance Registry System: 3,6-diamino-2,5-dichloro-1,4-hydroquinone(24118-25-0)

Safety Data

• Hazardous Substances Data: 24118-25-0(Hazardous Substances Data)

Upstream product

• 118-75-2 chloranil 
• 3908-48-3 2,5-diamino-3,6-dichloro-1,4-benzoquinone 

Downstream Products

• 1337927-53-3 4,8-dichloro-2,6-bis(chloromethyl)benzo[1,2-d;4,5-d']bisoxazole 
• 125659-91-8 (2,5-Bis-aziridin-1-yl-4-isobutoxycarbonylamino-3,6-dioxo-cyclohexa-1,4-dienyl)-carbamic acid isobutyl ester 
• 125671-99-0 (2,5-Bis-aziridin-1-yl-4-butoxycarbonylamino-3,6-dioxo-cyclohexa-1,4-dienyl)-carbamic acid butyl ester 
• 125659-90-7 (2,5-Bis-aziridin-1-yl-3,6-dioxo-4-propoxycarbonylamino-cyclohexa-1,4-dienyl)-carbamic acid propyl ester 
• 125659-88-3 (2,5-Dichloro-4-isobutoxycarbonylamino-3,6-dioxo-cyclohexa-1,4-dienyl)-carbamic acid isobutyl ester 
• 125659-87-2 (4-Butoxycarbonylamino-2,5-dichloro-3,6-dioxo-cyclohexa-1,4-dienyl)-carbamic acid butyl ester 
• 125659-89-4 (2,5-Bis-aziridin-1-yl-4-methoxycarbonylamino-3,6-dioxo-cyclohexa-1,4-dienyl)-carbamic acid methyl ester 
• 125659-86-1 (2,5-Dichloro-3,6-dioxo-4-propoxycarbonylamino-cyclohexa-1,4-dienyl)-carbamic acid propyl ester 
• 24118-24-9 2,5-dichloro-3,6-bis(methoxycarbonylamino)-1,4-benzoquinone 
• 33251-22-8 2,5-dichloro-3,6-bis(ethoxycarbonylamino)-1,4-benzoquinone 
• 57998-68-2 diaziquone 
• 125659-85-0 (2,5-Dichloro-3,6-dihydroxy-4-isobutoxycarbonylamino-phenyl)-carbamic acid isobutyl ester 
• 125659-83-8 (2,5-Dichloro-3,6-dihydroxy-4-propoxycarbonylamino-phenyl)-carbamic acid propyl ester 
• 125659-84-9 (4-Butoxycarbonylamino-2,5-dichloro-3,6-dihydroxy-phenyl)-carbamic acid butyl ester 

Relevant articles and documents

Tuning the optical and electronic properties of 4,8-disubstituted benzobisoxazoles via alkyne substitution

In an effort to design new electron-deficient building blocks for the synthesis of conjugated materials, a series of new trans-benzobisoxazoles bearing halogen or alkynyl substituents at the 4,8-positions was synthesized. Additionally, the impact of these modifications on the optical and electronic properties was investigated. Theoretical calculations predicted that the incorporation of various alkynes can be used to tune the energy levels and band gaps of these small molecules. The targeted 4,8-disubstituted benzobisoxazoles were easily prepared in good yields using a two-step reaction sequence: Lewis acid catalyzed orthoester cyclization followed by Sonogashira cross-coupling. The experimentally determined HOMO values for these 4,8-disubstituted benzobisoxazoles ranged from -4.97 to -6.20 eV and showed reasonable correlation to the theoretically predicted values, with a percent deviation that ranged from 2.4-12.8%. However, the deviation between actual and predicted HOMO values was reduced to less than 3.5% when the theoretical values were extrapolated to the long-chain limit and compared to copolymers containing the 4,8-disubstituted benzobisoxazoles. Collectively, these results indicate that these 4,8-disubstituted trans-benzobisoxazoles can be used for the synthesis of new conjugated materials with electronic properties that are variable and predictable.