24273-37-8Relevant articles and documents
Base-Catalysed Nitrosation of 1-Indanones - A Novel Ring Expansion Reaction
Chatterjea, Jnanendra Nath,Bhakta, Chittaranjan,Sinha, Anil Kumar,Jha, Hem Chandra,Zilliken, Fritz
, p. 52 - 57 (2007/10/02)
The 1-indanones 1-4, substituted in the five-membered ring, react with butyl nitrite in the presence of sodium methoxide to give exclusively the 2-hydroxyisocarbostyrils 8-11.In the absence of substituents (5-7) the reaction is accompanied by the formation of 2-hydroxyimino derivatives (22-24) which are obtained as main products.