24332-24-9

Basic information

• Product Name: 1-(hex-1-ynyl)cyclohexyl acetate
• Synonyms: 1-(hex-1-ynyl)cyclohexyl acetate
• CAS NO: 24332-24-9
• Molecular Weight: 222.327
• Mol File: 24332-24-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1-(hex-1-ynyl)cyclohexyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(hex-1-ynyl)cyclohexyl acetate(24332-24-9)
• EPA Substance Registry System: 1-(hex-1-ynyl)cyclohexyl acetate(24332-24-9)

Safety Data

• Hazardous Substances Data: 24332-24-9(Hazardous Substances Data)

Upstream product

• 693-02-7 hex-1-yne 
• 108-94-1 cyclohexanone 
• 108-24-7 acetic anhydride 
• 15332-33-9 1-(hex-1-ynyl)cyclohexanol 

Downstream Products

• 5452-52-8 2-cyclohexylidene-1-phenyl-1-ethanone 
• 136291-75-3 1-cyclohexylidene-1-fluorohexan-2-one 
• 1225432-41-6 1-bromo1-cyclohexylidene-n-hexan-2-one 
• 24332-28-3 (2-methyl-1-hexenylidene)-cyclohexane 

Relevant articles and documents

Domino gold-catalyzed rearrangement and fluorination of propargyl acetates

A combination of IPrAuNTf2 as catalyst in the presence of Selectfluor has been successfully used for the high yielding synthesis of α-fluoroenones via 1,3-acyloxy rearrangement of propargyl acetates followed by Csp2-F bond formation,

Gold-catalyzed efficient preparation of linear α-haloenones from propargylic acetates

Versatile linear α-iodo- and α-bromoenones are prepared efficiently from readily accessible propargylic acetates using 2 mol % of Au(PPh3)NTf2. This reaction is easy to execute and has broad substrate scope. Good to excellent Z-selectivities are observed in the cases of propargylic acetates derived from aliphatic aldehydes.

Gold-catalyzed efficient preparation of linear α-lodoenones from propargylic acetates

Only 2 mol % of Au(PPh3)NTf2 is needed to convert readily accessible propargylic acetates into versatile linear α-iodoenones in good to excellent yields. This reaction is easy to execute and has broad substrate scope. Good to excellent Z-selectivities are observed in the cases of aliphatic propargylic acetates derived from aldehydes.