24341-83-1

Basic information

• Product Name: 2-(4-chlorophenyl)-2,3-dihydrobenzo[d][1,3,2]diazaborinin-4(1H)-one
• Synonyms: 2-(4-chlorophenyl)-2,3-dihydrobenzo[d][1,3,2]diazaborinin-4(1H)-one
• CAS NO: 24341-83-1
• Molecular Weight: 256.499
• Mol File: 24341-83-1.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 2-(4-chlorophenyl)-2,3-dihydrobenzo[d][1,3,2]diazaborinin-4(1H)-one(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-chlorophenyl)-2,3-dihydrobenzo[d][1,3,2]diazaborinin-4(1H)-one(24341-83-1)
• EPA Substance Registry System: 2-(4-chlorophenyl)-2,3-dihydrobenzo[d][1,3,2]diazaborinin-4(1H)-one(24341-83-1)

Safety Data

• Hazardous Substances Data: 24341-83-1(Hazardous Substances Data)

Upstream product

• 1679-18-1 4-Chlorophenylboronic acid 
• 28144-70-9 anthranilic acid amide 

Downstream Products

• 1449074-36-5 C₁₉H₂₄BClN₂OSi 
• 1449074-45-6 C₁₃H₉BClIN₂O 
• 1296939-30-4 2-[4-chloro-2-(dimethylphenylsilyl)phenyl]-2,3-dihydrobenzo[d][1,3,2]diazaborinin-4(1H)-one 

Relevant articles and documents

Synthesis method of 1, 3, 2-benzodiazeborane and derivatives of 1, 3, 2-benzodiazeborane

The invention provides a synthesis method of 1, 3, 2-benzodiazepine and derivatives thereof, which comprises the following steps: carrying out dehydration condensation on phenylboronic acid and derivatives thereof, and anthranilamide and derivatives thereof in a solvent to obtain 1, 3, 2-benzodiazepine and derivatives thereof. According to the method, phenylboronic acid and derivatives thereof and anthranilamide and derivatives thereof are subjected to dehydration condensation in a solvent to obtain 1, 3, 2-benzodiazepine and derivatives thereof, and the method is mild in reaction condition, high in yield, low in cost and small in pollution, does not need any catalyst or other additives, and has the advantages of being simple in reaction operation and green.

An Efficient Ni/Pd Catalyzed Chemoselective Synthesis of 1,3,2-Benzodiazaborininones from Boronic Acids and Anthranilamides

An efficient Ni/Pd catalyzed chemoselective synthesis of 1,3,2-benzodiazaborininones from boronic acids and anthranilamide has been developed. This protocol allows for the rapid and straightforward access to a wide range of 1,3,2-benzodiazaborininones at roomtemperature with excellent functional group tolerance. (Figure presented.).

Anthranilamide-masked o-iodoarylboronic acids as coupling modules for iterative synthesis of ortho-linked oligoarenes

Anthranilamide (AAM)-masked o-iodoarylboronic acids were prepared from AAM-masked arylboronic acids via Rucatalyzed o-C-H silylation, followed by iododesilylation with ICl. The Suzuki-Miyaura coupling of AAM-masked o-haloarylboronic acids with arylboronic acids proceeded under ligandfree conditions. Oligo(o-phenylene)s and oligo(naphthalene-2,3-diyl)s were synthesized via iterative Suzuki-Miyaura coupling sequences.