24372-60-9

Basic information

• Product Name: 2-oxo-2-phenylethyl piperidine-1-carbodithioate
• Synonyms: Piperidine-1-carbodithioic acid 2-oxo-2-phenyl-ethyl ester
• CAS NO: 24372-60-9
• Molecular Formula: C₁₄H₁₇NOS₂
• Molecular Weight: 279.4209
• Mol File: 24372-60-9.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 417.5°C at 760 mmHg
• Flash Point: 206.3°C
• Density: 1.233g/cm³
• Vapor Pressure: 3.53E-07mmHg at 25°C
• Refractive Index: 1.63
• CAS DataBase Reference: 2-oxo-2-phenylethyl piperidine-1-carbodithioate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-oxo-2-phenylethyl piperidine-1-carbodithioate(24372-60-9)
• EPA Substance Registry System: 2-oxo-2-phenylethyl piperidine-1-carbodithioate(24372-60-9)

Safety Data

• Hazardous Substances Data: 24372-60-9(Hazardous Substances Data)

Upstream product

• 626-67-5 N-methylcyclohexylamine 
• 75-15-0 carbon disulfide 
• 70-11-1 α-bromoacetophenone 
• 49791-55-1 ammonium salt of N-piperidino dithiocarbamic acid 
• 110-89-4 piperidine 
• 100-42-5 styrene 
• 98-99-7 piperidine-1-carbodithioic acid 

Downstream Products

• 119824-94-1 α-(1,3-dithiolane-2-ylidene)-phenacyl-piperidino-dithiocarbamate 
• 119824-98-5 α-(1,3-dithiane-2-ylidene)-phenacyl-piperidino-dithiocarbamate 
• 88559-26-6 5-benzoyl-4-methylthio-1,3-dithiole-2-thione 
• 119824-90-7 S-(1-benzoyl-2-bis-methylthio)vinyl-piperidino-dithiocarbamate 

Relevant articles and documents

Visible-Light-Induced Photocatalytic Synthesis of β-Keto Dithiocarbamates via Difunctionalization of Styrenes

A facile photocatalyzed strategy for difunctionalization of styrenes in the presence of CS2 and amines providing β-keto dithiocarbamates has been developed. In the case of 4-nitrostyrene and 2-vinylpyridine, however, only 2-arylethylthiocarbamates are interestingly formed without the aid of photoredox catalysis/TBHP.

A new route to dithiocarbamates from tertiary N-methyl and N-benzylamines

The sequential treatment of various tertiary N-methyl and N-benzylamines with carbon disulfide, and then with an alkyl halide in tetrahydrofuran gave the corresponding dithiocarbamates in good to excellent yields.