24422-74-0

Basic information

• Product Name: erythro-1-phenylethyl phenyl sulfoxide
• Synonyms: erythro-1-phenylethyl phenyl sulfoxide
• CAS NO: 24422-74-0
• Molecular Weight: 230.331
• Mol File: 24422-74-0.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: erythro-1-phenylethyl phenyl sulfoxide(CAS DataBase Reference)
• NIST Chemistry Reference: erythro-1-phenylethyl phenyl sulfoxide(24422-74-0)
• EPA Substance Registry System: erythro-1-phenylethyl phenyl sulfoxide(24422-74-0)

Safety Data

• Hazardous Substances Data: 24422-74-0(Hazardous Substances Data)

Upstream product

• 98-80-6 phenylboronic acid 
• 108-98-5 thiophenol 
• 6099-23-6 1-(phenylsulfinyl)acetophenone 
• 585-71-7 (1-bromoethyl)benzne 
• 40390-78-1 [(1-phenylethyl)thio]benzene 
• 67300-99-6 1-phenylethenylmagnesium bromide 
• 670-98-4 methyl benzenesulfinate 
• 51207-25-1 ethylphenylsulfoxide 
• 7417-81-4 benzyl phenyl sulfoxide 
• 74-88-4 methyl iodide 
• 49833-32-1 1-phenyl-1-(phenylsulfinyl)-ethene 
• 26910-34-9 α-Bromoethyl phenyl sulfoxide 

Downstream Products

• 1212-08-4 S-Phenyl benzenethiosulfonate 
• 98-85-1 1-Phenylethanol 
• 1208-20-4 S-phenyl benzenethiosulfinate 
• 100-42-5 styrene 
• 882-33-7 diphenyldisulfane 
• 1859-03-6 ethyl benzenesulfinate 
• 16336-45-1 α-phenylthiostyrene 

Relevant articles and documents

A route to benzylic arylsulfoxides from β-ketosulfoxides

The K2CO3-mediated benzylation of β-ketosulfoxides 4 with 2.0?equiv of benzylic halides 5 affords benzylic arylsulfoxides 6 in moderate yields along with trace amounts of chalcones 7. The products 6 are assumed to form in situ intermediates of sulfenate anions from β-ketosulfoxides which are commonly involved in carbon–sulfur bond formation. A plausible mechanism has been proposed.

Palladium-catalyzed suzuki-miyaura reaction involving a secondary sp 3 carbon: Studies of stereochemistry and scope of the reaction

Palladium-catalyzed C-C bond formation involving secondary sp 3-hybridized carbon is described. These reactions occur with secondary 1-bromoethyl arylsulfoxides and different arylboronic acids, to produce the corresponding arylated sulfoxides in moderate to high yields and with complete stereospecificity. Despite the presence of β hydrogens in the substrate, the competitive β-hydride elimination is not a significant side reaction when coordinating solvents are used. The reported cross-coupling involves secondary Csp3-Csp2 bond formation: this is the first time that a mechanistic study has been carried out with such substrates. The reaction proceeds with inversion of configuration at the stereogenic C sp3 carbon. The high stereospecificity of the coupling and the mildness of the reaction conditions allow for the preservation of the optical purities of reagents and products and the preparation of useful chiral targets.

Efficient and selective sulfoxidation by hydrogen peroxide, using a recyclable flavin-[BMIm]PF6 catalytic system

A new flavin catalyst 2 immobilized in an ionic liquid ([BMIm]PF 6) was used for the highly selective oxidation of sulfides to sulfoxides by hydrogen peroxide. The sulfoxides were obtained in good to high yields and high selectivity without any