244239-16-5

Basic information

• Product Name: ethyl 6-(4-nitrophenyl)-4,5-(1-propanyl-3-yliden)-1,4,5,6-tetrahydro-3-pyridinecarboxylate
• Synonyms: ethyl 6-(4-nitrophenyl)-4,5-(1-propanyl-3-yliden)-1,4,5,6-tetrahydro-3-pyridinecarboxylate
• CAS NO: 244239-16-5
• Molecular Weight: 314.341
• Mol File: 244239-16-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ethyl 6-(4-nitrophenyl)-4,5-(1-propanyl-3-yliden)-1,4,5,6-tetrahydro-3-pyridinecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 6-(4-nitrophenyl)-4,5-(1-propanyl-3-yliden)-1,4,5,6-tetrahydro-3-pyridinecarboxylate(244239-16-5)
• EPA Substance Registry System: ethyl 6-(4-nitrophenyl)-4,5-(1-propanyl-3-yliden)-1,4,5,6-tetrahydro-3-pyridinecarboxylate(244239-16-5)

Safety Data

• Hazardous Substances Data: 244239-16-5(Hazardous Substances Data)

Upstream product

• 152975-95-6 4-(Ethoxycarbonyl)-1,1-diphenyl-1-methyl-2-aza-1λ⁵-phosphabuta-1,3-diene 
• 7148-07-4 1-pyrrolidinocyclopent-1-ene 
• 182418-46-8 (E)-3-{[1-(4-Nitro-phenyl)-meth-(E)-ylidene]-amino}-acrylic acid ethyl ester 

Relevant articles and documents

Reaction of N-vinylic phosphazenes derived from β-amino acids with aldehydes. Azadiene-mediated synthesis of dihydropyridines, pyridines, and polycyclic nitrogen derivatives

Enamino phosphonium salts 2 are obtained by 1,2-addition of hydrogen chloride to N-vinylic phosphazenes 1 derived from triphenylphosphine. Aza- Wittig reaction of phosphazenes 1 derived from triphenylphosphine and 6 derived from diphenylmethylphosphine with aldehydes 3 leads to the formation of 2-azadienes 7. Reaction of azadienes 7 with enamines affords dihydropyridines 9 and 11, pyridines 12, and bicyclic nitrogen heterocycles 15-18 in a regioselective fashion, while heterodiene 20 reacts in the same way with pyrrolidinocyclohexanone giving 1-azaphenanthrene compound 21. Reaction of enamino phosphonium salts 2 with aldehydes 3 gives symmetrical dihydropyridines 5.