244251-95-4

Basic information

• Product Name: 2-hydroxypropyl 4-nitrobenzoate
• CAS NO: 244251-95-4
• Molecular Weight: 225.201
• Mol File: 244251-95-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-hydroxypropyl 4-nitrobenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-hydroxypropyl 4-nitrobenzoate(244251-95-4)
• EPA Substance Registry System: 2-hydroxypropyl 4-nitrobenzoate(244251-95-4)

Safety Data

• Hazardous Substances Data: 244251-95-4(Hazardous Substances Data)

Upstream product

• 57-55-6 propylene glycol 
• 619-73-8 4-nitrobenzyl chloride 
• 65513-22-6 4-methyl-2-(4-nitro-phenyl)-[1,3]dioxolane 

Relevant articles and documents

Pd-Colloids-Catalyzed/Ag2O-Oxidized General and Selective Esterification of Benzylic Alcohols

Palladium colloids obtained from the degradation of Hermann–Beller palladacycle proved to be an efficient catalytic system in combination with silver oxide as a selective oxidant for the oxidative esterification of differently substituted benzyl alcohols in MeOH as solvent. Excellent reactivity exhibited by the catalytic system also allowed the alcoholic coupling partner to be changed from MeOH to a wide range of alcohols having diverse functionalities. The mildness of the developed protocol also made it possible to employ propargyl alcohol as the coupling partner without any observation of any interference of the terminal alkyne. Selective oxidative coupling of a primary alcoholic functional group over secondary in the case of glycols and glycerols was also made possible using the developed catalyst system. To test the relevancy of Pd/Ag combined catalysis mixed Pd/Ag colloids were synthesized, characterized by TEM, XRD and XPS and applied to oxidative-esterification successfully.

2-Iodoxybenzoic acid/tetraethylammonium bromide/water: An efficient combination for oxidative cleavage of acetals

A simple and efficient procedure has been developed for the oxidation of cyclic and acyclic acetals to the corresponding hydroxyalkyl carboxylic esters and simple esters, respectively. 2-Iodoxybenzoic acid (IBX) in the presence of tetraethylammonium bromide was employed for the reaction in aqueous media. The salient features of the protocol include short reaction time, environmentally benign reagents and solvent, and moderate to high yields. Georg Thieme Verlag Stuttgart.