24455-26-3

Basic information

• Product Name: S,S-di-p-tolyl carbonodithioate
• Synonyms: S,S-di-p-tolyl carbonodithioate
• CAS NO: 24455-26-3
• Molecular Weight: 274.408
• Mol File: 24455-26-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: S,S-di-p-tolyl carbonodithioate(CAS DataBase Reference)
• NIST Chemistry Reference: S,S-di-p-tolyl carbonodithioate(24455-26-3)
• EPA Substance Registry System: S,S-di-p-tolyl carbonodithioate(24455-26-3)

Safety Data

• Hazardous Substances Data: 24455-26-3(Hazardous Substances Data)

Upstream product

• 140-89-6 potassium ethyl xanthogenate 
• 2028-84-4 p-methylbenzenediazonium chloride 
• 75-44-5 phosgene 
• 106-45-6 para-thiocresol 
• 24455-28-5 di-4-tolyl trithiocarbonate 
• 530-62-1 1,1'-carbonyldiimidazole 
• 17241-10-0 tris(p-tolylthio)methane 
• 16754-59-9 tris-isopropylsulfanyl-methane 
• 108-98-5 thiophenol 
• 4832-52-4 tris(phenylthio)methane 
• 24455-24-1 S,S-di-p-tolyl ethanebis(thioate) 

Downstream Products

• 106-45-6 para-thiocresol 

Relevant articles and documents

A Mild Method for Access to α-Substituted Dithiomalonates through C-Thiocarbonylation of Thioester: Synthesis of Mesoionic Insecticides

An efficient method for targeting a variety of symmetrical and asymmetrical α-substituted dithiomalonates (DTMs) is described, utilizing 1H-imidazole-1-carbothioates as reactive acylating agents and MgBr2?OEt2/DBU or LiHMDS for soft or hard enolization conditions of thioesters, respectively. The utility of this methodology was demonstrated through the synthesis of the pyridopyrimidine mesoionic insecticides: triflumezopyrim and dicloromezotiaz. (Figure presented.).

NOVEL DESULFURIZATION OF THIOCARBONYL COMPOUNDS INTO THEIR CARBONYL COMPOUNDS WITH TERTIARY BUTYL THIONITRATE

Various thiocarbonyl compounds such as thioamides, thiocarbamate, thiocarbonate, trithiocarbonate and thioketone were readily reacted with t-butyl thionitrate (t-BuSNO2) to give the corresponding carbonyl compounds in excellent yields under mild conditions.Desulfurization seems to be initiated via the selective nitrosation on the sulfur atom of thiocarbonyl group with t-BuSNO2.

N-NITROSAMINES AS REAGENTS FOR THE =C=S=C=O TRANSFORMATION

N-nitrosopiperidine and N-nitroso-N-methylaniline react in acidic solution with thiocarbonyl compounds to give the corresponding carbonyl analogues.Secondary- and tertiary thioamides, xanthione, thio- and dithiobutyrolactone, thiocoumarin, certain thiourea derivatives, dithio-O,O-thiocarbonic, S,S-trithiocarbonic- and N,N disubstituted thiocarbamic esters are all converted into the corresponding O-analogues.Thiobenzamide and N-phenylthiourea yield 1,2,4-thiadiazoles.All the reactions are run with iodide (I-) as NO+-carrier.The kinetics of the reaction have been studied under pseudo-first order conditions, and the reaction rate is proportional to the Pearson's nucleophilicity parameter of ions.The =C=S =C=O transformation is also found to take place in gastric juice.