24456-27-7

Basic information

• Product Name: 1,2-bis(diphenylphosphino)ethane bis(borane)
• Synonyms: 1,2-bis(diphenylphosphino)ethane bis(borane)
• CAS NO: 24456-27-7
• Molecular Weight: 426.094
• Mol File: 24456-27-7.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1,2-bis(diphenylphosphino)ethane bis(borane)(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-bis(diphenylphosphino)ethane bis(borane)(24456-27-7)
• EPA Substance Registry System: 1,2-bis(diphenylphosphino)ethane bis(borane)(24456-27-7)

Safety Data

• Hazardous Substances Data: 24456-27-7(Hazardous Substances Data)

Upstream product

• 16940-66-2 sodium tetrahydroborate 
• 7553-56-2 iodine 
• 1663-45-2 1,2-bis-(diphenylphosphino)ethane 
• 13292-87-0 dimethylsulfide borane complex 
• 54067-17-3 diphenylmethylphosphine-borane complex 
• 83095-83-4 [platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)] 
• 14044-65-6 borane-THF 
• 41593-58-2 diphenylphosphineborane 
• 4559-70-0 Diphenylphosphine oxide 
• 2129-89-7 diphenyl(methyl)phosphine oxide 

Downstream Products

• 944069-66-3 (C₆H₅)2PCH₂CH₂P(C₆H₅)2BH₂(H)BH₂⁽¹⁺⁾*B(C₆F₅)4^(1-)=((C₆H₅)4P₂C₂H₉B₂)B(C₆F₅)4 
• 4141-50-8 1,2-bis(diphenylphosphinoyl)ethane 
• 7615-76-1 1,2-bis(diphenylphosphinothioyl)ethane 
• 1663-45-2 1,2-bis-(diphenylphosphino)ethane 

Relevant articles and documents

[{(dppe)Pt}2B7H11]: An arachno-bimetallanonaborane based on the uncommon n-B9H15 cluster framework

The first bimetallanonaborane, [{(dppe)Pt)2B7B11], based on the uncommon n-B9H15 cluster framework, is prepared and characterized as a final product from the reaction of pentaborane (9) with [PtCl2(dppe)].

Direct use of chiral or achiral organophosphorus boranes as pro-ligands for transition metal catalyzed reactions

Chiral or achiral organophosphorus borane complexes were used without isolation of the free tricoordinate P(III) ligand; thus, the borane adducts could be used either directly with metal salts to perform the catalysis, or they could be decomplexed by DABCO, or cyclooctadiene, and used in situ to generate the catalytic species. Chiral copper, palladium and rhodium complexes prepared using this method, were tested in asymmetric organometallic catalyzed 1,4-addition to 2-cyclohexenone, allylation of Schiff base and hydrogenation of α-acetamidocinnamic acid derivatives, respectively.

Phosphine Oxides and LiAlH4-NaBH4-CeCl3: Synthesis and Reactions of Phosphine-Boranes

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