245551-47-7

Basic information

• Product Name: [(η(5)-C5Me5)TiF(μ-F)(μ-OSO2-p-C6H4CH3)]2
• CAS NO: 245551-47-7
• Molecular Weight: 784.605
• Mol File: 245551-47-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(η(5)-C5Me5)TiF(μ-F)(μ-OSO2-p-C6H4CH3)]2(CAS DataBase Reference)
• NIST Chemistry Reference: [(η(5)-C5Me5)TiF(μ-F)(μ-OSO2-p-C6H4CH3)]2(245551-47-7)
• EPA Substance Registry System: [(η(5)-C5Me5)TiF(μ-F)(μ-OSO2-p-C6H4CH3)]2(245551-47-7)

Safety Data

• Hazardous Substances Data: 245551-47-7(Hazardous Substances Data)

Upstream product

• 17872-98-9 4-Methyl-1-benzolsulfonsaeure-trimethylsilylester 

Relevant articles and documents

Synthesis and structural characterization of sulfonates, phosphinates and carboxylates of organometallic group 4 metal fluorides

Reaction of [Cp*TiF3] (Cp* = (η5-C5Me5)) with Me3SiOSO2-p-C6H4CH3, Me3SiOPOPh2 and 1,2-(Me3SiOCO)2C6H4 yields the dinuclear complexes [{Cp*TiF(μ-F)(μ-OSO2-p-C6H4CH 3)}2] (1), [{Cp*TiF(μ-F)(μ-OPOPh2)}2] (2) and [(Cp*TiF(μ-F)(μ-OCO-o-C6H4CO 2SiMe3)}2] (3). The molecular structures of 1 and 2 have been determined by single-crystal X-ray analysis. In complexes 1-3, the two titanium atoms are connected by bridging fluorine atoms as well as bridging sulfonate, phosphinate and carboxylate groups respectively. Each titanium atom is also bonded to a terminal fluorine atom. Reaction of [Cp2*ZrF2] with 1,2-(Me3SiOCO)2C6H4 leads to the mononuclear pentacoordinate 18-electron species [Cp2*ZrF(μ-OCO-o-C6H4CO 2SiMe3)] (4) and its structure was determined by X-ray crystallographic methods.